Taichi Kano
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Explore the profile of Taichi Kano including associated specialties, affiliations and a list of published articles.
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90
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367
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Recent Articles
1.
Kunitomo N, Kano T
J Org Chem
. 2024 Jul;
89(15):11048-11052.
PMID: 38995617
The Cu-catalyzed asymmetric conjugate addition of arylboronic acids to enone diesters is reported. This operationally simple and scalable reaction proceeded under mild conditions. The practical utility of this approach was...
2.
Hikima R, Takeshima A, Kano T
Org Biomol Chem
. 2023 Oct;
21(42):8463-8466.
PMID: 37830372
Polysubstituted furans were synthesized in one-pot through the EtZn-mediated coupling reaction between dibromoketones and monobromo carbonyl compounds and the subsequent β-elimination with bromoacetyl bromide. Polysubstituted pyrroles were also prepared in...
3.
Tsuzuki S, Kano T
Org Lett
. 2023 Sep;
25(36):6677-6681.
PMID: 37671853
Metal- and additive-free transsulfinamidation of N-unsubstituted sulfinamides and -pivaloyl-protected sulfinamides with various amines is reported. With this method, both -monosubstituted and ,-disubstituted sulfinamides were obtained in good yields simply by...
4.
Uwaso Y, Yokoyama N, Kano T
Org Biomol Chem
. 2023 Aug;
21(32):6484-6487.
PMID: 37526571
Novel axially chiral biphenyl-based amine catalysts have been designed and synthesized from dibromopyrenes. These chiral amines function as effective catalysts for asymmetric reactions through enamine intermediates.
5.
Hikawa R, Shimogaki M, Kano T
Chem Commun (Camb)
. 2023 Jun;
59(54):8424-8427.
PMID: 37334826
Three contiguous stereocenters were constructed by an amino acid-catalyzed asymmetric aldol reaction of α-siloxyketones with racemizable α-haloaldehydes dynamic kinetic resolution. One-pot catalytic asymmetric synthesis of the highly functionalized products could...
6.
Yasumoto K, Kunitomo N, Kano T
Org Lett
. 2023 Mar;
25(9):1497-1502.
PMID: 36861961
The Cu-catalyzed asymmetric conjugate addition of trialkenylboroxines to enone diesters is reported. This operationally simple and scalable reaction proceeded at room temperature, and a wide range of enone diesters and...
7.
Tsuzuki S, Kano T
Angew Chem Int Ed Engl
. 2023 Feb;
62(16):e202300637.
PMID: 36807500
Chiral sulfimides, the aza-analogues of sulfoxides, are valuable compounds in organic synthesis and medicinal chemistry. Herein, we report an efficient method for preparing chiral sulfimides from easily available enantioenriched sulfinamides....
8.
Takeshima A, Kano T
Angew Chem Int Ed Engl
. 2022 Dec;
62(8):e202217496.
PMID: 36583678
A novel route to synthesize 1,4-dicarbonyl compounds is described. α,α-Dibromoketones generate zinc enolates through a diethylzinc-mediated halogen-metal exchange and react with α-bromocarbonyl compounds to furnish 1,4-dicarbonyl compounds via a second...
9.
Golub T, Kano T, Maruoka K, Merten C
Chem Commun (Camb)
. 2022 Jul;
58(60):8412-8415.
PMID: 35796225
We present a VCD spectroscopic characterization of a chiral 1,1'-binaphthyl azepine catalyst and show that the VCD spectra of an generated enamine and an prepared iminium ion are characteristically different....
10.
Maeda Y, Hamada S, Aota Y, Otsubo K, Kano T, Maruoka K
J Org Chem
. 2022 Jan;
87(5):3652-3660.
PMID: 35075904
Chiral sulfoximines have recently been considered as promising bioisosteres in medicinal chemistry. However, methods for preparing chiral sulfoximines in a stereoselective manner are underdeveloped. Herein, we demonstrate an asymmetric synthesis...