Taichi Kano
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Explore the profile of Taichi Kano including associated specialties, affiliations and a list of published articles.
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90
Citations
367
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Recent Articles
11.
Tsuzuki S, Sakurai S, Matsumoto A, Kano T, Maruoka K
Chem Commun (Camb)
. 2021 Jul;
57(64):7942-7945.
PMID: 34286742
A Ni-catalyzed direct C-H alkylation of N-quinolylbenzamides using alkylsilyl peroxides as alkyl-radical precursors is described. The reaction forms a new C(sp3)-C(sp2) bond via the selective cleavage of both C(sp3)-C(sp3) and...
12.
Homma C, Takeshima A, Kano T, Maruoka K
Chem Sci
. 2021 Jun;
12(4):1445-1450.
PMID: 34163907
Stereoselective Mannich reactions of aldehydes with ketimines provide chiral β-amino aldehydes that bear an α--amine moiety. However, the structural variation of the ketimines is limited due to the formation of...
13.
Homma C, Kano T, Maruoka K
Chem Commun (Camb)
. 2021 Feb;
57(22):2808-2811.
PMID: 33600542
A bifunctional amino sulfonamide-catalyzed asymmetric conjugate addition of aldehydes to alkenyl alkynyl ketimines as reactive surrogates for enones has been developed. Use of a phenylcyclopropane-based amino sulfonamide catalyst, which can...
14.
Asymmetric α-Hydroxylation of α-Aryl-δ-lactams with Molecular Oxygen under Phase-Transfer Conditions
Inukai T, Kano T, Maruoka K
Org Lett
. 2021 Jan;
23(3):792-796.
PMID: 33476160
An asymmetric synthesis of α-aryl-α-hydroxy-δ-lactams via phase-transfer-catalyzed hydroxylation with molecular oxygen is described. High yields and high enantioselectivities were achieved using 2,2-diarylvinyl group as an achiral auxiliary. This strategy allows...
15.
Sakurai S, Kano T, Maruoka K
Chem Commun (Camb)
. 2020 Dec;
57(1):81-84.
PMID: 33290475
A Cu-catalyzed O-alkylation of phenol derivatives using alkylsilyl peroxides as alkyl radical precursors is described. The reaction proceeds smoothly under mild reaction conditions and the use of two different ligands...
16.
Mochimatsu T, Aota Y, Kano T, Maruoka K
Chem Asian J
. 2020 Oct;
15(22):3816-3819.
PMID: 33025747
α-Functionalization of ketones in an umpolung fashion can be achieved by nucleophilic addition to the oxy-allyl cation intermediate. However, applicable carbon nucleophiles are limited to ones with high nucleophilicity. Additionally,...
17.
Sakurai S, Matsumoto A, Kano T, Maruoka K
J Am Chem Soc
. 2020 Oct;
142(45):19017-19022.
PMID: 33017146
Transition-metal-catalyzed radical relay coupling reactions have recently emerged as one of the most powerful methods to achieve difunctionalization of olefins. However, there has been limited success in applying this method...
18.
Yasumoto K, Kano T, Maruoka K
J Org Chem
. 2020 Jul;
85(15):10232-10239.
PMID: 32614186
The axially chiral biphenols are known as a broadly applicable chiral source. However, only a few electron-deficient ones have been reported to date. In the present study, chiral biphenols having...
19.
Bai J, Zhao L, Wang F, Yan F, Kano T, Maruoka K, et al.
Org Lett
. 2020 Jun;
22(14):5439-5445.
PMID: 32598844
We report the chiral phosphoric acid catalyzed formal (3 + 2) cycloaddition of 3-substituted 1-indoles and propargylic alcohols containing a functional directing group (-NHAc or -OH). This work represents a...
20.
Inukai T, Kano T, Maruoka K
Angew Chem Int Ed Engl
. 2019 Nov;
59(6):2211-2214.
PMID: 31769914
A highly enantioselective synthesis of δ-lactams having a chiral quaternary carbon center at the α-position has been developed through an asymmetric alkylation of 3-arylpiperidin-2-ones under phase-transfer conditions. In this transformation,...