Stephen W Laws
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Explore the profile of Stephen W Laws including associated specialties, affiliations and a list of published articles.
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5
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27
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Recent Articles
1.
Zhu J, Laws S, Rourke M, Scheidt K
Green Synth Catal
. 2021 Sep;
1(1):70-74.
PMID: 34485961
Recent advances in photocatalysis have enabled radical methods with complementary chemoselectivity to established two electron bond forming approaches. While this radical strategy has previously been limited to substrates with favorable...
2.
Laws S, Howard S, Mato R, Meng S, Fettinger J, Shaw J
Org Lett
. 2019 Jun;
21(13):5073-5077.
PMID: 31247788
The organocatalytic synthesis of densely substituted mono- and bis-γ-lactams involving the Mukaiyama Mannich addition of 2,5-bis(trimethylsilyloxy)furan to imines is described. Use of a ditoluenesulfonylimide catalyst produces γ-lactams from monoaddition, whereas...
3.
Laws S, Moore L, Di Maso M, Nguyen Q, Tantillo D, Shaw J
Org Lett
. 2017 May;
19(10):2466-2469.
PMID: 28474515
A diastereoselective base-catalyzed Mannich reaction of cyclic, enolizable anhydrides and N-sulfonyl imines for the synthesis of δ-lactams is reported. This anhydride Mannich reaction tolerates imines derived from aryl and enolizable...
4.
Laws S, Scheerer J
J Org Chem
. 2013 Jan;
78(6):2422-9.
PMID: 23360221
The asymmetric total synthesis of the chlorinated [2.2.2]-diazabicyclic indole alkaloid (+)-malbrancheamide B is reported. Key to the synthesis is a domino reaction sequence that employs an aldol condensation, alkene isomerization,...
5.
Margrey K, Chinn A, Laws S, Pike R, Scheerer J
Org Lett
. 2012 May;
14(10):2458-61.
PMID: 22571782
A domino reaction sequence involving aldol condensation, alkene isomerization, and intramolecular hetero-Diels-Alder cycloaddition for the synthesis of [2.2.2]-diazabicyclic structures is reported. Excellent diastereofacial control during the cycloaddition is enforced with...