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Rint P Sijbesma

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Articles 97
Citations 1277
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Recent Articles
1.
Schara P, Cristadoro A, Sijbesma R, Tomovic Z
ChemSusChem . 2024 Aug; 18(2):e202401595. PMID: 39141831
Polyurethanes (PUs) are highly versatile polymers widely utilized across industries. However, chemical recycling of PU poses significant challenges due to the harsh conditions required and the formation of complex mixtures...
2.
Wink R, Majumdar S, van Benthem R, Heuts J, Sijbesma R
Polym Chem . 2023 Nov; 14(37):4294-4302. PMID: 38013800
Neighboring group assisted rearrangement substantially increases relaxation rates in dynamic covalent networks, allowing easier (re)processing of these materials. In this work, we introduce a dynamic covalent network with anionic phosphate...
3.
Zhang H, van Hertrooij A, Schnitzer T, Chen Y, Majumdar S, van Benthem R, et al.
Macromolecules . 2023 Aug; 56(16):6452-6460. PMID: 37637305
In dynamic polyamide networks, 1,2,4,5-benzene tetraamide (B4A) units act simultaneously as a dynamic covalent cross-linker and as supramolecular stacking motif. This results in materials with a rubbery plateau modulus that...
4.
Liu J, Zhang Y, van Dongen K, Kennedy C, Schotman M, Marin San Roman P, et al.
Biomacromolecules . 2023 May; 24(6):2447-2458. PMID: 37246400
Two synthetic supramolecular hydrogels, formed from bis-urea amphiphiles containing lactobionic acid (LBA) and maltobionic acid (MBA) bioactive ligands, are applied as cell culture matrices . Their fibrillary and dynamic nature...
5.
Liu J, Lou X, Schotman M, Marin San Roman P, Sijbesma R
Gels . 2022 Oct; 8(10). PMID: 36286116
The design of photo-responsive supramolecular hydrogels based on coumarin dimerization and de-dimerization is described. The photo-responsive coumarin unit is chemically incorporated into an oligo(ethylene glycol) (OEG) bis-urea amphiphile that is...
6.
Majumdar S, Zhang H, Soleimani M, van Benthem R, Heuts J, Sijbesma R
ACS Macro Lett . 2022 Jun; 9(12):1753-1758. PMID: 35653678
Dynamic covalent networks are a class of polymeric materials that combine the merits of classical thermosets and thermoplastics, in terms of mechanical properties and reprocessability, in one material. Various dynamic...
7.
Zhang H, Majumdar S, van Benthem R, Sijbesma R, Heuts J
ACS Macro Lett . 2022 May; 9(2):272-277. PMID: 35638690
Dynamic covalent bonds in a polymer network lead to plasticity, reshapability, and potential recyclability at elevated temperatures in combination with solvent-resistance and better dimensional stability at lower temperatures. Here we...
8.
Hu H, Cheng X, Ma Z, Sijbesma R, Ma Z
J Am Chem Soc . 2022 May; 144(22):9971-9979. PMID: 35617457
Real-time monitoring of strain/stress in polymers is a big challenge to date. Herein, we for the first time report an ESIPT (excited-state intramolecular proton transfer)-based mechanochromic mechanophore (MM). The synthesis...
9.
Li H, Gostl R, Delgove M, Sweeck J, Zhang Q, Sijbesma R, et al.
ACS Macro Lett . 2022 May; 5(9):995-998. PMID: 35614648
Optical reporting of covalent bond scission in self-assembled structures in water is an important step toward the detection of forces in biological systems. Here we show that micelles of a...
10.
Groote R, Jakobs R, Sijbesma R
ACS Macro Lett . 2022 May; 1(8):1012-1015. PMID: 35607027
In this work, we demonstrate that the performance of mechanochemically activated transesterification and alkene metathesis catalysts is significantly enhanced when the thermal effects of ultrasound are suppressed. Suppression of these...