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Paul Demay-Drouhard

Explore the profile of Paul Demay-Drouhard including associated specialties, affiliations and a list of published articles. Areas
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Recent Articles
1.
Daaoub A, Morris J, Beland V, Demay-Drouhard P, Hussein A, Higgins S, et al.
Angew Chem Int Ed Engl . 2023 Apr; 62(24):e202302150. PMID: 37029093
Most studies in molecular electronics focus on altering the molecular wire backbone to tune the electrical properties of the whole junction. However, it is often overlooked that the chemical structure...
2.
Laturski A, Gaffen J, Demay-Drouhard P, Caputo C, Baumgartner T
Precis Chem . 2023 Apr; 1(1):49-56. PMID: 37025975
Various methods have been developed to measure the strength of a Lewis acid. A major challenge for these measurements lies in the complexity that arises from variable solvent interactions and...
3.
Demay-Drouhard P, Baumgartner T
J Org Chem . 2020 Oct; 85(22):14627-14633. PMID: 33052689
The unexpectedly challenging synthesis of 4-pyridyl-extended dithieno[3,2-:2',3'-]phospholes via Stille cross-coupling is reported. The optical and electrochemical properties of the phosphoryl-bridged species were studied experimentally and computationally, and their properties were...
4.
Demay-Drouhard P, Ching H, Decroos C, Guillot R, Li Y, Tabares L, et al.
Phys Chem Chem Phys . 2020 Sep; 22(36):20792-20800. PMID: 32909565
The 285 GHz EPR spectra of perchlorotriphenylmethyl and tetrathiatriarylmethyl radicals in frozen solution have been accurately measured. The relationship between their molecular structures and their g-tensors has been investigated with...
5.
Du K, Demay-Drouhard P, Samanta K, Li S, Thikekar T, Wang H, et al.
J Org Chem . 2020 Aug; 85(17):11368-11374. PMID: 32820630
To investigate the dynamic stereochemical inversion behavior of pillar[5]arenes (P[5]s) in more detail, we synthesized a series of novel rim-differentiated P[5]s with various substituents and examined their rapid rotations by...
6.
Demay-Drouhard P, Du K, Samanta K, Wan X, Yang W, Srinivasan R, et al.
Org Lett . 2019 Apr; 21(11):3976-3980. PMID: 31002251
The development of an efficient synthetic route toward rim-differentiated C-symmetric pillar[5]arenes (P[5]s), whose two rims are decorated with different chemical functionalities, opens up successive transformations of this macrocyclic scaffold. This...
7.
Guo M, Wang X, Zhan C, Demay-Drouhard P, Li W, Du K, et al.
J Am Chem Soc . 2017 Dec; 140(1):74-77. PMID: 29220153
The synthesis of "rim-differentiated" C-symmetric pillar[5]arenes, whose two rims are decorated with different chemical functionalities, has remained a challenging task. This is due to the inherent statistical nature of the...
8.
Demay-Drouhard P, Ching H, Akhmetzyanov D, Guillot R, Tabares L, Bertrand H, et al.
Chemphyschem . 2016 Mar; 17(13):2066-78. PMID: 27017296
High-spin gadolinium(III) and manganese(II) complexes have emerged as alternatives to standard nitroxide radical spin labels for measuring nanometric distances by using pulsed electron-electron double resonance (PELDOR or DEER) at high...
9.
Ching H, Mascali F, Bertrand H, Bruch E, Demay-Drouhard P, Rasia R, et al.
J Phys Chem Lett . 2016 Mar; 7(6):1072-6. PMID: 26938795
A genetically encodable paramagnetic spin-label capable of self-assembly from naturally available components would offer a means for studying the in-cell structure and interactions of a protein by electron paramagnetic resonance...
10.
Ching H, Demay-Drouhard P, Bertrand H, Policar C, Tabares L, Un S
Phys Chem Chem Phys . 2015 Aug; 17(36):23368-77. PMID: 26287752
Pulse electron-electron double resonance (PELDOR) is a versatile technique for probing the structures and functions of complex biological systems. Despite the recent interest in high-spin metal-ions for high field/frequency applications,...