Yogesh Siddaraju
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Explore the profile of Yogesh Siddaraju including associated specialties, affiliations and a list of published articles.
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12
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40
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Recent Articles
1.
Cohen A, Siddaraju Y, Marek I
Org Lett
. 2022 Nov;
24(45):8322-8325.
PMID: 36354275
We report the directed diastereoselective Simmons-Smith cyclopropanation and vanadium-catalyzed epoxidation reactions of alkenyl cyclopropyl carbinol derivatives. The reaction furnished densely substituted stereodefined bicyclopropanes and cyclopropyl oxiranes as a single diastereomer...
2.
Siddaraju Y, Sabbatani J, Cohen A, Marek I
Angew Chem Int Ed Engl
. 2022 May;
61(28):e202203652.
PMID: 35521738
The diastereoselective double carbometalation reaction of cyclopropenes provides, in a single-pot operation, two ω-ene-[1,1]-bicyclopropyl ester derivatives. One regioisomer then undergoes a Pd-catalyzed addition of aryl iodide to provide skipped dienes...
3.
Siddaraju Y, Prabhu K
ACS Omega
. 2019 Aug;
3(5):4908-4917.
PMID: 31458707
Metal-free chemoselective hydroamination of styrene derivatives has been achieved with high chemoselectivity over sulfenylation of 1-tetrazole-5-thiol using a catalytic amount of iodine. The scope of this methodology has been extended...
4.
Siddaraju Y, Prabhu K
J Org Chem
. 2018 Jul;
83(18):11145-11153.
PMID: 30032620
A chemoselective formation of C-N bond catalyzed by iodine has been developed using heterocyclic thiols and thiones. The reaction occurs at the nitrogen center over the sulfur, leading to the...
5.
Siddaraju Y, Prabhu K
J Org Chem
. 2018 Feb;
83(5):2986-2992.
PMID: 29389131
A rare regioselective sulfenylation of α'-CH or α'-CH bonds adjacent to α,β-unsaturated ketones using dimethyl sulfoxide as an oxidant and a substoichiometric amount of aq HI as an additive is...
6.
Siddaraju Y, Prabhu K
Org Biomol Chem
. 2017 Jun;
15(24):5191-5196.
PMID: 28590497
An iodine catalyzed sulfenylation of pyrazolones with a diverse range of heterocyclic thiols, heterocyclic thiones and disulfides has been described using dimethyl sulfoxide as an oxidant, which is an inexpensive,...
7.
Siddaraju Y, Prabhu K
J Org Chem
. 2017 Feb;
82(6):3084-3093.
PMID: 28229592
Synthesis of polyfunctionalized aminothioalkenes has been demonstrated using iodine as a catalyst (30 mol %) and dimethyl sulfoxide as an oxidant under metal-free reaction conditions. This methodology allows a facile...
8.
Siddaraju Y, Prabhu K
Org Lett
. 2016 Dec;
18(23):6090-6093.
PMID: 27934388
A metal-free regioselective sulfenylation of the α-CH group of ketones has been achieved in the presence of the α-CH or α-CH group using the cross dehydrogenative (CDC) strategy. Aldehydes also...
9.
Siddaraju Y, Prabhu K
J Org Chem
. 2016 Aug;
81(17):7838-46.
PMID: 27490357
A regioselective formation of C-S bonds has been achieved using a cross dehydrogenative coupling (CDC) protocol using iodine as a catalyst and dimethyl sulfoxide as an oxidant under green chemistry...
10.
Siddaraju Y, Prabhu K
Org Biomol Chem
. 2015 Oct;
13(48):11651-6.
PMID: 26467572
Tetrabutyl ammonium iodide (TBAI) catalyzed α-aminoxylation of ketones using aq. TBHP as an oxidant has been accomplished. We have shown that the CDC (cross dehydrogenative coupling) reactions of ketones with...