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Wen-Yan Tong

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Articles 8
Citations 22
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Recent Articles
1.
Tong W, Su X, Sun P, Xu S, Qu S, Wang X
J Org Chem . 2023 Oct; 88(21):15404-15413. PMID: 37853516
This density functional theory study explores the detailed mechanism of nickel-catalyzed hydroalkylation of the C═C bond of N-Cbz-protected enamines (Cbz = benzyloxycarbonyl) with alkyl iodides to give chiral α-alkyl amines....
2.
Jin H, Tong W, Zhang J, Rudolph M, Rominger F, Shen X, et al.
Nat Commun . 2022 Mar; 13(1):1672. PMID: 35354823
Pt(II) and Au(III)-mediated intermolecular divergent annulations of benzofurazans and ynamides highlighted the N- to O-selectivity of tunable metal carbene intermediates. PtCl with a bulky phosphite ligand resulted in the specific...
3.
Wang X, Tong W, Huang B, Cao S, Li Y, Jiao J, et al.
J Am Chem Soc . 2022 Mar; 144(11):4952-4965. PMID: 35274949
We report a general protocol for the convergent synthesis of 1,4-dicarbonyl -alkenes form alkynes using α-diazo sulfonium triflate and water. The C═O, C═C, and C-H bonds are formed under mild...
4.
Bian J, Tong W, Pitsch C, Wu Y, Wang X
Dalton Trans . 2021 Feb; 50(7):2654-2662. PMID: 33527940
We present a detailed DFT mechanistic study on the first Ni-catalyzed direct carbonyl-Heck coupling of aryl triflates and aldehydes to afford ketones. The precatalyst Ni(COD)2 is activated with the phosphine...
5.
Cheng H, Yang Z, Chen R, Cao L, Tong W, Wei Q, et al.
Angew Chem Int Ed Engl . 2020 Nov; 60(10):5141-5146. PMID: 33252181
Reported here is a concise total synthesis of (-)-berkelic acid in eight linear steps. This synthesis features a Catellani reaction/oxa-Michael cascade for the construction of the isochroman scaffold, a one-pot...
6.
Tong W, Ly T, Zhao T, Wu Y, Wang X
Chem Commun (Camb) . 2019 Dec; 56(1):113-116. PMID: 31793572
We report on the basis of DFT computations a plausible and detailed reaction mechanism for the first Pd-catalyzed decarbonylative phosphorylation of amides forming C-P bonds, which reveals, among other things,...
7.
Tong W, Zhao T, Zhao X, Wang X, Wu Y, Yuan C
Dalton Trans . 2019 Sep; 48(42):15802-15809. PMID: 31560356
Ultrashort metal-metal distances (USMMDs, d < 1.900 Å) have been realized computationally between the main group metal beryllium. However, due to their ionic charge state and the insufficient stability of...
8.
Zhao T, Zhao X, Bian J, Tong W, Jin B, Wang X, et al.
Dalton Trans . 2019 Apr; 48(19):6581-6587. PMID: 31016316
A current project in metal-metal bonding chemistry is to achieve ultrashort metal-metal distances (USMMDs, denoted by dM-M < 1.900 Å) between main group metal beryllium atoms. A valid way for...