Shuanglin Qu
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Explore the profile of Shuanglin Qu including associated specialties, affiliations and a list of published articles.
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21
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109
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Recent Articles
1.
Li W, Wei H, Wang B, He X, Jiang Y, Nie M, et al.
Angew Chem Int Ed Engl
. 2025 Feb;
:e202424209.
PMID: 39930319
In this study, we have discovered the versatility of the dithiosulfonate reagent (ArSO-SSR) in transition metal catalyzed selective hydrodisulfuration of unactivated alkenes. The hydrodisulfuration displays a unique Markovnikov selectivity with...
2.
Tong W, Su X, Sun P, Xu S, Qu S, Wang X
J Org Chem
. 2023 Oct;
88(21):15404-15413.
PMID: 37853516
This density functional theory study explores the detailed mechanism of nickel-catalyzed hydroalkylation of the C═C bond of N-Cbz-protected enamines (Cbz = benzyloxycarbonyl) with alkyl iodides to give chiral α-alkyl amines....
3.
Tang L, Huang Q, Wu F, Xiao Y, Zhou J, Xu T, et al.
Chem Sci
. 2023 Sep;
14(36):9696-9703.
PMID: 37736637
Ring-opening of bicyclo[1.1.0]butanes (BCBs) is emerging as a powerful strategy for 1,3-difunctionalized cyclobutane synthesis. However, reported radical strain-release reactions are typically plagued with diastereoselectivity issues. Herein, an atom-economic protocol for...
4.
Jin H, Tong W, Zhang J, Rudolph M, Rominger F, Shen X, et al.
Nat Commun
. 2022 Mar;
13(1):1672.
PMID: 35354823
Pt(II) and Au(III)-mediated intermolecular divergent annulations of benzofurazans and ynamides highlighted the N- to O-selectivity of tunable metal carbene intermediates. PtCl with a bulky phosphite ligand resulted in the specific...
5.
Wang X, Tong W, Huang B, Cao S, Li Y, Jiao J, et al.
J Am Chem Soc
. 2022 Mar;
144(11):4952-4965.
PMID: 35274949
We report a general protocol for the convergent synthesis of 1,4-dicarbonyl -alkenes form alkynes using α-diazo sulfonium triflate and water. The C═O, C═C, and C-H bonds are formed under mild...
6.
Ji Y, Li J, Li C, Qu S, Zhang B
Org Lett
. 2020 Dec;
23(1):207-212.
PMID: 33305569
A visible-light-promoted method for generating amidyl radicals from -fluorosulfonamides via a manganese-catalyzed N-F bond activation strategy is reported. This protocol employs a simple manganese complex, Mn(CO), as the precatalyst and...
7.
Cheng H, Yang Z, Chen R, Cao L, Tong W, Wei Q, et al.
Angew Chem Int Ed Engl
. 2020 Nov;
60(10):5141-5146.
PMID: 33252181
Reported here is a concise total synthesis of (-)-berkelic acid in eight linear steps. This synthesis features a Catellani reaction/oxa-Michael cascade for the construction of the isochroman scaffold, a one-pot...
8.
A near-infrared fluorogenic probe with fast response for detecting sodium dithionite in living cells
Yu X, Xiang L, Yang S, Qu S, Zeng X, Zhou Y, et al.
Spectrochim Acta A Mol Biomol Spectrosc
. 2020 Sep;
245:118887.
PMID: 32927301
Developing a reliable fluorescence probe is crucial for accurately monitoring sodium dithionite (NaSO, SDT) in biosystems, but the current reported azo-based ones suffers from short excitation/emission wavelengths and relative slow...
9.
Liu R, Li J, Sun J, Liu X, Qu S, Li P, et al.
Angew Chem Int Ed Engl
. 2020 Jan;
59(11):4428-4433.
PMID: 31912602
A simple and efficient protocol to generate amidyl radicals from amine functionalities through a manganese-mediated atom-transfer reaction has been developed. This approach employs an earth-abundant and inexpensive manganese complex, Mn...
10.
Li J, Qu S, Zhao W
Angew Chem Int Ed Engl
. 2019 Dec;
59(6):2360-2364.
PMID: 31799790
A rhodium-catalyzed remote C(sp )-H borylation of silyl enol ethers (SEEs, E/Z mixtures) by alkene isomerization and hydroboration is reported. The reaction exhibits mild reaction conditions and excellent functional-group tolerance....