Jonathan C Axtell
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Explore the profile of Jonathan C Axtell including associated specialties, affiliations and a list of published articles.
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21
Citations
284
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Recent Articles
1.
Kataki-Anastasakou A, Jia S, Axtell J, Sletten E
Isr J Chem
. 2023 Aug;
63(1-2).
PMID: 37636996
Metabolic incorporation of unnatural functionality on glycans has allowed chemical biologists to observe and affect cellular processes. Recent work has resulted in glycan-fluorophore structures that allow for direct visualization of...
2.
Mu X, Hopp M, Dziedzic R, Waddington M, Rheingold A, Sletten E, et al.
Organometallics
. 2021 May;
39(23):4380-4386.
PMID: 34012188
Over the past several years, a number of strategies for the functionalization of dicarba--dodecaboranes (carboranes) have emerged. Despite these developments, B - N bond formation on the carborane scaffold remains...
3.
Dziedzic R, Axtell J, Rheingold A, Spokoyny A
Org Process Res Dev
. 2021 Mar;
23(8):1638-1645.
PMID: 33776400
Off-cycle processes in catalytic reactions can dramatically influence the outcome of the chemical transformation and affect its yield, selectivity, rate, and product distribution. While the generation of off-cycle intermediates can...
4.
Kataki-Anastasakou A, Axtell J, Hernandez S, Dziedzic R, Balaich G, Rheingold A, et al.
J Am Chem Soc
. 2020 Nov;
142(49):20513-20518.
PMID: 33253553
High-affinity guests have been reported for the macrocyclic host cucurbit[7]uril (CB[7]), enabling widespread applications, but hindering CB[7] materials from being returned to their guest-free state for reuse. Here, we present...
5.
Aubry T, Winchell K, Salamat C, Basile V, Lindemuth J, Stauber J, et al.
Adv Funct Mater
. 2020 Jul;
30(28):2001800.
PMID: 32684909
Carrier mobility in doped conjugated polymers is limited by Coulomb interactions with dopant counterions. This complicates studying the effect of the dopant's oxidation potential on carrier generation because different dopants...
6.
Stauber J, Schwan J, Zhang X, Axtell J, Jung D, McNicholas B, et al.
J Am Chem Soc
. 2020 Jul;
142(30):12948-12953.
PMID: 32646209
While the icosahedral -[BH] cluster does not display reversible electrochemical behavior, perfunctionalization of this species via substitution of all 12 B-H vertices with alkoxy or benzyloxy (OR) substituents engenders reversible...
7.
Mu X, Axtell J, Bernier N, Kirlikovali K, Jung D, Umanzor A, et al.
Chem
. 2020 Apr;
5(9):2461-2469.
PMID: 32292833
A cornerstone of modern synthetic chemistry rests on the ability to manipulate the reactivity of a carbon center by rendering it either electrophilic or nucleophilic. However, accessing a similar reactivity...
8.
Anderson K, Mills H, Mao C, Kirlikovali K, Axtell J, Rheingold A, et al.
Tetrahedron
. 2019 Jul;
75(2):187-191.
PMID: 31303685
Carboranes are boron-rich molecular clusters possessing electronic characteristics that allow for orthogonal approaches to vertex-selective modifications. We report improved functionalization methods utilizing orthogonal chemistry to achieve efficient substitution at electron-rich...
9.
Axtell J, Messina M, Liu J, Galaktionova D, Schwan J, Porter T, et al.
Inorg Chem
. 2019 Jun;
58(16):10516-10526.
PMID: 31247818
Redox-active proanions of the type B(OCHAr) [Ar = CF (), 4-CFCH (), 3,5-(CF)CH ()] are introduced in the context of an experimental and computational study of the visible-light-initiated polymerization of...
10.
Yruegas S, Axtell J, Kirlikovali K, Spokoyny A, Martin C
Chem Commun (Camb)
. 2019 Feb;
55(20):2892-2895.
PMID: 30706915
The synthesis of [1,1'-bis(o-carboranyl)]boranes was achieved through the deprotonation of 1,1'-bis(o-carborane) reagents followed by salt metathesis with (iPr)2NBCl2. X-ray crystallography confirms planar central BC4 rings and Gutmann-Beckett studies reveal an...