Jonathan C Axtell
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Explore the profile of Jonathan C Axtell including associated specialties, affiliations and a list of published articles.
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21
Citations
284
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Recent Articles
11.
Aubry T, Axtell J, Basile V, Winchell K, Lindemuth J, Porter T, et al.
Adv Mater
. 2019 Jan;
31(11):e1805647.
PMID: 30672037
One of the most effective ways to tune the electronic properties of conjugated polymers is to dope them with small-molecule oxidizing agents, creating holes on the polymer and molecular anions....
12.
Axtell J, Saleh L, Qian E, Wixtrom A, Spokoyny A
Inorg Chem
. 2018 Feb;
57(5):2333-2350.
PMID: 29465227
This Viewpoint describes major advances pertaining to perfunctionalized boron clusters in synthesis and their respective applications. The first portion of this work highlights key synthetic methods, allowing one to access...
13.
Dziedzic R, Martin J, Axtell J, Saleh L, Ong T, Yang Y, et al.
J Am Chem Soc
. 2017 May;
139(23):7729-7732.
PMID: 28541671
We report the first observed Pd-catalyzed isomerization ("cage-walking") of B(9)-bromo-meta-carborane during Pd-catalyzed cross-coupling, which enables the formation of B-O and B-N bonds at all boron vertices (B(2), B(4), B(5), and...
14.
Qian E, Wixtrom A, Axtell J, Saebi A, Jung D, Rehak P, et al.
Nat Chem
. 2017 May;
9(4):333-340.
PMID: 28485398
The majority of biomolecules are intrinsically atomically precise, an important characteristic that enables rational engineering of their recognition and binding properties. However, imparting a similar precision to hybrid nanoparticles has...
15.
Kirlikovali K, Axtell J, Gonzalez A, Phung A, Khan S, Spokoyny A
Chem Sci
. 2017 Feb;
7(8):5132-5138.
PMID: 28191302
We report the synthesis and characterization of a series of d metal complexes featuring robust and photophysically innocent strong-field chelating 1,1'-bis(-carborane) () ligand frameworks. A combination of UV-Vis spectroscopy, single...
16.
Axtell J, Kirlikovali K, Djurovich P, Jung D, Nguyen V, Munekiyo B, et al.
J Am Chem Soc
. 2016 Dec;
138(48):15758-15765.
PMID: 27934013
We report the development of a new class of phosphorescent zwitterionic bis(heteroleptic) Ir(III) compounds containing pyridyl ligands with weakly coordinating nido-carboranyl substituents. Treatment of phenylpyridine-based Ir(III) precursors with C-substituted ortho-carboranylpyridines...
17.
Wixtrom A, Shao Y, Jung D, Machan C, Kevork S, Qian E, et al.
Inorg Chem Front
. 2016 Nov;
3(5):711-717.
PMID: 27885335
We have developed a fast and efficient route to obtain perfunctionalized ether-linked alkyl and benzyl derivatives of the -[B(OH)] icosahedral dodecaborate cluster via microwave-assisted synthesis. These icosahedral boron clusters exhibit...
18.
Dziedzic R, Saleh L, Axtell J, Martin J, Stevens S, Royappa A, et al.
J Am Chem Soc
. 2016 Jul;
138(29):9081-4.
PMID: 27384544
Carboranes are boron-rich molecules that can be functionalized through metal-catalyzed cross-coupling. Here, for the first time, we report the use of bromo-carboranes in palladium-catalyzed cross-coupling for efficient B-N, B-O, and...
19.
Messina M, Axtell J, Wang Y, Chong P, Wixtrom A, Kirlikovali K, et al.
J Am Chem Soc
. 2016 May;
138(22):6952-5.
PMID: 27186856
We report a discovery that perfunctionalized icosahedral dodecaborate clusters of the type B12(OCH2Ar)12 (Ar = Ph or C6F5) can undergo photo-excitation with visible light, leading to a new class of...
20.
Axtell J, Schrock R, Muller P, Smith S, Hoveyda A
Organometallics
. 2014 Oct;
33(19):5342-5348.
PMID: 25328268
Tungsten NAr alkylidene complexes have been prepared that contain the electron-withdrawing Ar groups 2,4,6-XCH (Ar, X = Cl, Br), 2,6-Cl-4-CFCH (Ar), and 3,5-(CF)CH (Ar). Reported complexes include W(NAr)Cl(dme) (dme =...