Jin-Sheng Yu
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Explore the profile of Jin-Sheng Yu including associated specialties, affiliations and a list of published articles.
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41
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148
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Recent Articles
11.
Zhang X, Gao Y, Zhang Y, Zhou J, Yu J
Angew Chem Int Ed Engl
. 2023 Jan;
62(9):e202217724.
PMID: 36625565
We report the first highly enantioselective construction of silicon-stereocenters by asymmetric enamine catalysis. An unprecedented desymmetric intramolecular aldolization of prochiral siladials was thus developed for the facile access of multifunctional...
12.
Liao L, Zhang Y, Wu Z, Ye Z, Zhang X, Chen G, et al.
Chem Sci
. 2022 Nov;
13(42):12519-12526.
PMID: 36382272
A highly enantio- and regio-selective Markovnikov hydromonofluoro(methyl)alkylation of 1,3-dienes was developed using redox-neutral nickel catalysis. It provided a facile strategy to construct diverse monofluoromethyl- or monofluoroalkyl-containing chiral allylic molecules. Notably,...
13.
Lei C, Wang X, Mu B, Yu J, Zhou Y, Zhou J
Org Lett
. 2022 Nov;
24(45):8364-8369.
PMID: 36318643
An unprecedented tandem trifluoromethylsilylation/intramolecular S2 substitution sequence was realized by using bifunctional reagent Me(CHCl)SiCF, allowing efficient construction of valuable trifluoromethylated oxasilacyclohexanes that are difficult to access by known methods. Initial...
14.
Mu B, Gao Y, Yang F, Wu W, Zhang Y, Wang X, et al.
Angew Chem Int Ed Engl
. 2022 Jul;
61(38):e202208861.
PMID: 35880539
We report the development of bifunctional trifluoromethylsilyl reagents for selective trifluoromethylation. The newly developed reagent, Me (CH Cl)SiCF , allows highly enantioselective trifluoromethylations of ketones with broad scope. Notably, by...
15.
Wu W, Mu B, Yu J, Zhou J
Chem Sci
. 2022 Apr;
13(12):3519-3525.
PMID: 35432855
A bifunctional silyl reagent Me(CH[double bond, length as m-dash]CH)SiCN has been developed as a novel ethylene equivalent for the Diels-Alder (DA) reaction. The use of this reagent enables the controllable...
16.
Xu P, Cui X, Chen C, Zhou F, Yu J, Ao Y, et al.
Org Lett
. 2021 Oct;
23(21):8471-8476.
PMID: 34644098
Here, we report an unprecedented catalytic enantioselective cyanation of ketonitrones enabled by the bifunctional cyanating reagent Me(CHCl)SiCN. This approach allows facile access to optically active -hydroxyl-α-amino nitriles that are of...
17.
Lei C, Mu B, Zhou F, Yu J, Zhou Y, Zhou J
Chem Commun (Camb)
. 2021 Sep;
57(73):9178-9191.
PMID: 34519317
Since the discovery of carbocations in 1901, the past 120 years have witnessed many marvelous advances in the chemistry of carbocations. The state-of-the-art research in this field is to overcome...
18.
He J, Zhang Z, Mu B, Cui X, Zhou J, Yu J
J Org Chem
. 2021 Jun;
86(13):9206-9217.
PMID: 34126743
An unprecedented catalyst-free reaction of benzo[]thiophene-2,3-diones with difluoroenoxysilanes has been developed using either MeOH or HO as the solvent, which constitutes a facile and efficient protocol for the solvent-controlled divergent...
19.
Ding P, Zhou F, Wang X, Zhao Q, Yu J, Zhou J
Chem Sci
. 2021 Jun;
11(15):3852-3861.
PMID: 34122853
The development of catalyst-controlled stereodivergent asymmetric catalysis is important for providing facile access to all stereoisomers of chiral products with multiple stereocenters from the same starting materials. Despite progress, new...
20.
Shi Y, Pan B, He J, Zhou Y, Zhou J, Yu J
J Org Chem
. 2021 May;
86(11):7797-7805.
PMID: 34000179
The -site reactivity of difluoroenoxysilanes is disclosed for the first time, which enabled the direct construction of versatile -difluoroalkenes through an unprecedented highly efficient addition reaction with ketenes. A series...