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Jian-Xing Xu

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Articles 30
Citations 174
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Recent Articles
1.
Yuan Y, Xu J, Wu X
Chem Commun (Camb) . 2022 Oct; 58(86):12110-12113. PMID: 36226440
We report here a cooperative Cu/Pd-catalyzed multi-component borocarbonylation of ethylene with aryl iodides. A variety of synthetically useful β-boryl ketones were assembled from the most basic C1 (CO) and C2...
2.
Xu J, Wang L, Wu X
Chem Asian J . 2022 Sep; 17(22):e202200928. PMID: 36102174
Carbonylative multi-component reactions (CMCR), having four or more kinds of starting materials, provide an efficient strategy for the preparation of polyfunctional carbonylated compounds. Diverse CMCR utilizing non-noble transition-metal catalysts have...
3.
Zhang Y, Bao Z, Xu J, Wu X
Org Lett . 2022 Sep; 24(37):6845-6850. PMID: 36098561
A palladium-catalyzed perfluoroalkylative carbonylation of 2-allylaryl trifluoromethanesulfonates has been developed. A range of 2-allyl trifluoromethanesulfonates, perfluoroalkyl halides, and amines were applied in this tandem procedure to provide the corresponding β-perfluoroalkyl...
4.
Xu J, Wang L, Wu X
Org Lett . 2022 Jun; 24(26):4820-4824. PMID: 35739644
A palladium-catalyzed desulfonative carbonylation of thiosulfonates has been explored. Without any additive, a series of -aryl/alkyl benzenesulfonothioates were successfully transformed to thioesters in moderate to excellent yields by SO extrusion...
5.
Kuai C, Xu J, Chen B, Wu X
Org Lett . 2022 Jun; 24(24):4464-4469. PMID: 35694976
α,β-Unsaturated amides play a vital role in natural products, pharmaceuticals, organic synthesis, and functional materials. Herein, we disclosed a regio- and stereoselective hydroaminocarbonylation of unsymmetrical internal alkynes via palladium catalysis...
6.
Long P, Xu J, Bai X, Xu Z, Zheng Z, Yang K, et al.
RSC Adv . 2022 May; 8(41):22944-22951. PMID: 35540169
To shed light on the influence of reaction parameters on palladium-catalyzed tandem allylic alkylation in the presence of Fei-Phos (a chiral -1,2-diaminocyclohexane-derived phosphine ligand), the effect of different phosphine ligands,...
7.
Xu J, Kuai C, Wu X
J Org Chem . 2022 Apr; 87(9):6371-6377. PMID: 35468297
Direct conversion of raw materials to fine chemicals is greatly economically influential. We developed a non-expensive cobalt-catalyzed multicomponent carbonylative reaction for the synthesis of γ-aryl carboxylic acid esters from readily...
8.
Xu J, Bao Z, Wu X
Org Lett . 2022 Feb; 24(9):1848-1852. PMID: 35212225
Transforming carbon monoxide (C1) and ethylene (C2) into high value-added chemicals is of great significance from an economic perspective, especially to multifunctionalized C3 compounds. Herein, we developed a palladium-catalyzed thiocarbonylative...
9.
Kuai C, Wang L, Xu J, Wu X
Org Lett . 2021 Dec; 24(1):451-456. PMID: 34931845
The selective and effective conversion of low-cost and simple bulk chemicals into high value-added products through catalytic strategy has a wide range of practical significance. Here, a palladium-catalyzed method for...
10.
Xu J, Zhao F, Wu X
Org Biomol Chem . 2020 Dec; 18(48):9796-9799. PMID: 33295924
A method for palladium-catalyzed carbonylative C-S bond activation of divinyl sulfides to synthesize numerous tert-(E)-butyl arylacry-lates under 1 bar of CO has been developed. Employing electron-rich NHC as the ligand,...