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David O Miller

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Articles 31
Citations 154
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Recent Articles
11.
Kudale A, Kendall J, Miller D, Collins J, Bodwell G
J Org Chem . 2008 Sep; 73(21):8437-47. PMID: 18821803
Condensation of 3-aminocoumarin (5) with 4-nitrobenzaldehyde (8) afforded a 2-azadiene (9), which reacted with various electron-rich alkenes (10 examples) in the presence of Yb(OTf)3 to afford 1,2,3,4-tetrahydropyrido[2,3-c]coumarins. Yields were generally...
12.
Dang A, Miller D, Dawe L, Bodwell G
Org Lett . 2007 Dec; 10(2):233-6. PMID: 18092790
Several 4-methoxyxanthones and 3,4-dimethoxyxanthones were synthesized in good yield via inverse-electron-demand Diels-Alder (IEDDA) driven domino reactions between a series of electron-deficient chromone-fused dienes with 1-(2,2-dimethoxyvinyl)pyrrolidine or tetramethoxyethene, respectively.
13.
Niel V, Milway V, Dawe L, Grove H, Tandon S, Abedin T, et al.
Inorg Chem . 2007 Dec; 47(1):176-89. PMID: 18076158
"Tritopic" picolinic dihydrazone ligands with tridentate coordination pockets are designed to produce homoleptic [3 x 3] nonanuclear square grid complexes on reaction with transition-metal salts, and many structurally documented examples...
14.
Al-Saraierh H, Miller D, Georghiou P
J Org Chem . 2007 May; 72(12):4532-5. PMID: 17488125
Narrow-rim 1,3-bis(phenylethynyl)-p-tert-butylcalix[4]arenes were found to be photolabile, producing unprecedented seven-membered oxacyclic systems formed via 7-exo-dig cyclizations and a new [3.2.1]bicyclic system via subsequent 1,8-H shifts. The calixarene provided a scaffold...
15.
Milway V, Abedin S, Niel V, Kelly T, Dawe L, Dey S, et al.
Dalton Trans . 2006 Jun; (23):2835-51. PMID: 16751892
Flat, quantum dot like arrays of closely spaced, electron rich metal centres are seen as attractive subunits for device capability at the molecular level. Mn(II)9 grids, formed by self-assembly processes...
16.
Abedin T, Thompson L, Miller D
Chem Commun (Camb) . 2005 Dec; (44):5512-4. PMID: 16358046
An oxalic dihydrazide based flexible polydentate amidrazone ligand undergoes spontaneous [2 x 2] grid assembly, followed by partial disassembly, and then reassembly in the presence of Co(NO3)2.6H2O and NH4(NCS) to...
17.
Al-Saraierh H, Miller D, Georghiou P
J Org Chem . 2005 Oct; 70(21):8273-80. PMID: 16209567
The narrow (or "lower")-rim hydroxyl groups of calixarenes are known to be resistant to substitution/displacement. The Sonogashira coupling reaction with TMSA and phenylacetylene, however, has now been extended to the...
18.
Tran A, Miller D, Georghiou P
J Org Chem . 2005 Feb; 70(4):1115-21. PMID: 15704943
[picture: see text] The syntheses of the first 2,3-dialkoxy-substituted naphthalene ring-based macrocycles which have calixarene-like structures are reported. The complexation properties of these octahomotetraoxaisocalix[4]naphthalenes were investigated. These new members of...
19.
Milway V, Thompson L, Miller D
Chem Commun (Camb) . 2004 Aug; (16):1790-1. PMID: 15306885
A sterically encumbered 'tritopic' picolinic-dihydrazone ligand reacts with cobalt(ii) nitrate in air to give a dodecanuclear [Co(ii)(6)Co(iii)(6)] cluster, in which six ligands are hydrolyzed to mono-carboxylate analogues.
20.
Zhao L, Niel V, Thompson L, Xu Z, Milway V, Harvey R, et al.
Dalton Trans . 2004 Jul; (9):1446-55. PMID: 15252640
Polynuclear manganese(II), cobalt(II)/(III), iron(II)/(III) and nickel(II) complexes of a group of flexible polydentate dihydrazone ligands, based on pyridine-2,6-dipicolinic (A), oxalic (B) and malonic (C) subunits are described. Structural details are...