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Basker Sundararaju

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Articles 46
Citations 294
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Recent Articles
1.
Pradhan S, Satav D, Dutta S, Maity B, Cavallo L, Sundararaju B
Nat Commun . 2024 Nov; 15(1):10421. PMID: 39613777
Skipped dienes are among the most prevalent motifs in a vast array of natural products, medicinal compounds, and fatty acids. Herein, we disclose a straightforward one-step reductive protocol under Co/PC...
2.
Vineet Kumar D, Sundararaju B
J Org Chem . 2024 Jul; 89(14):10087-10092. PMID: 38982582
Herein, we report a manganese-catalyzed -selective hydroarylation of allenyl ethylene carbonates (AECs) under mild conditions. The methodology employs an earth-abundant Mn(I)-catalyst, which shows high functional group tolerance, performed at room...
3.
Das A, Kumaran S, Ravi Sankar H, Premkumar J, Sundararaju B
Angew Chem Int Ed Engl . 2024 Jun; 63(40):e202406195. PMID: 38896502
In this study, we unveil a novel method for the asymmetric dearomatization of indoles under cobalt/photoredox catalysis. By strategically activating C-H bonds of amides and subsequent migratory insertion of π-bonds...
4.
Garai B, Das A, Vineet Kumar D, Sundararaju B
Chem Commun (Camb) . 2024 Mar; 60(25):3354-3369. PMID: 38441168
While progress in enantioselective C-H functionalization has been accomplished by employing 4d and 5d transition metal-based catalysts, the rapid depletion of these metals in the earth's crust poses a serious...
5.
Tafese B, Ganesh T, Solomon A, Sundararaju B, Garg N, Alebachew B
Langmuir . 2023 Dec; 40(1):72-83. PMID: 38147594
Carbon quantum dots have a great application potential in environmental protection via adsorption technology due to their large specific surface area and negative zeta potential. In this work, nitrogen and...
6.
Das A, Mandal R, Ravi Sankar H, Kumaran S, Premkumar J, Borah D, et al.
Angew Chem Int Ed Engl . 2023 Dec; 63(6):e202315005. PMID: 38095350
Metal-catalyzed asymmetric C-H bond annulation strategy offers a versatile platform, allowing the construction of complex P-chiral molecules through atom- and step-economical fashion. However, regioselective insertion of π-coupling partner between M-C...
7.
Dahiya P, Garg N, Poli R, Sundararaju B
Dalton Trans . 2023 Oct; 52(41):14752-14756. PMID: 37814805
To realize the goal of a carbon-free energy economy, it is crucial to discover reactions that utilize sustainable resources as alternatives to fossil feedstocks. In this study, a well-defined, air-stable...
8.
Pradhan S, Chakraborty P, Paira S, Sundararaju B
J Org Chem . 2023 Apr; 88(9):5893-5899. PMID: 37071873
Allenyl carbonate was used as a 1,3-butadiene surrogate to develop a photocatalytically sustainable protocol for cobalt-catalyzed crotylation of aldehydes. The developed method tolerated a wide range of aromatic and aliphatic...
9.
Garai B, Ali M, Mandal R, Sundararaju B
Org Lett . 2023 Mar; 25(12):2018-2023. PMID: 36926924
The C(8)-selective nucleophilic cascade cyclization of quinoline -oxide with easily derived 1,6-enyne from phenol derivatives is demonstrated. A variety of quinoline -oxide and alkynes are discovered to be suitable for...
10.
Garg N, Somasundharam H, Dahiya P, Sundararaju B
Chem Commun (Camb) . 2022 Aug; 58(71):9930-9933. PMID: 35979880
The described system offers an ideal, user-friendly protocol for the chemoselective homogeneous hydrogenation of α,β-unsaturated ketones at room temperature using methanol as a liquid organic hydrogen carrier. Excellent yields were...