Basker Sundararaju
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Explore the profile of Basker Sundararaju including associated specialties, affiliations and a list of published articles.
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46
Citations
294
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Recent Articles
11.
Emayavaramban B, Chakraborty P, Dahiya P, Sundararaju B
Org Lett
. 2022 Aug;
24(33):6219-6223.
PMID: 35960264
A mild, environmentally benign approach for α-methylation of ketones utilizing methanol as the C1 source under visible light has been developed. The reaction conditions were favorable for a wide range...
12.
C-H bond functionalization by dual catalysis: merging of high-valent cobalt and photoredox catalysis
Chakraborty P, Mandal R, Paira S, Sundararaju B
Chem Commun (Camb)
. 2021 Nov;
57(97):13075-13083.
PMID: 34779804
The merger of transition metal catalysis and photocatalysis has emerged as a versatile platform that opened the gateway to diverse low-energy pathways for several synthetic transformations. However, amidst the first-row...
13.
Mandal R, Barsu N, Garai B, Das A, Perekalin D, Sundararaju B
Chem Commun (Camb)
. 2021 Nov;
57(91):12167-12170.
PMID: 34726212
A new protocol is developed for the mono- and bis--C-H alkynylation of easily accessible benzamide derivatives using alkynyl bromides at room temperature by merging cobalt and photocatalysts. The diverse reactivity...
14.
Bandyopadhyay U, Sundararaju B, Poli R, Manoury E, Daran J
Acta Crystallogr E Crystallogr Commun
. 2021 Aug;
77(Pt 8):853-856.
PMID: 34422314
As a follow-up to our research on the chemistry of disubstituted ferrocene derivatives, the synthesis and the structure of the title compound, 2-(di-phenyl-phosphino-thio-yl)-2-(3-oxobut-1-en-yl)ferrocene, [Fe(CH)(CHOPS)], are described. The mol-ecule is built...
15.
Mandal R, Garai B, Sundararaju B
J Org Chem
. 2021 Jul;
86(14):9407-9417.
PMID: 34213334
An efficient protocol for the synthesis of biologically essential pyrroloquinolinones has been developed under Cp*Co catalysis, which involves a cascade reaction of C(7)-H alkenylation with alkynes followed by nucleophilic addition....
16.
Kalsi D, Barsu N, Chakrabarti S, Dahiya P, Rueping M, Sundararaju B
Chem Commun (Camb)
. 2019 Sep;
55(77):11626-11629.
PMID: 31502608
A mild, environment-friendly protocol has been developed to carry out the [4+2] annulation of aryl amides with unactivated olefins. A range of sterically and electronically diverse aryl amides and unactivated...
17.
Chakraborty P, Gangwar M, Emayavaramban B, Manoury E, Poli R, Sundararaju B
ChemSusChem
. 2019 Jun;
12(15):3463-3467.
PMID: 31240858
Although α-alkylation of ketones with primary alcohols by transition-metal catalysis is well-known, the same process with secondary alcohols is arduous and complicated by self-condensation. Herein a well-defined, high-valence cobalt(III)-catalyst was...
18.
Emayavaramban B, Chakraborty P, Sundararaju B
ChemSusChem
. 2018 Nov;
12(13):3089-3093.
PMID: 30418691
Direct reductive alkylation of amines with carboxylic acid is carried out by using an inexpensive, air-stable cobalt/triphos catalytic system with molecular hydrogen as the reductant. This efficient synthetic method proceeds...
19.
Gangwar M, Dahiya P, Emayavaramban B, Sundararaju B
Chem Asian J
. 2018 Jun;
13(17):2445-2448.
PMID: 29863804
A novel, well-defined molecular Cp*Co complex was isolated and structurally characterized for the first time. The efficiency of this cobalt catalyst was demonstrated in the alcohol dehydrogenation and dehydrative coupling...
20.
Mandal R, Emayavaramban B, Sundararaju B
Org Lett
. 2018 May;
20(10):2835-2838.
PMID: 29737172
A novel protocol for ortho-C-H alkylation of aromatic and heteroaromatic ketones and esters under Cp*Co(III) catalysis has been developed for the first time. The reaction proceeds through initial cyclometalation via...