Aman A Desai
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Explore the profile of Aman A Desai including associated specialties, affiliations and a list of published articles.
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10
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61
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Recent Articles
1.
Battula S, Desai A, Soni J, Mehta D
ACS Omega
. 2022 Feb;
7(6):5069-5078.
PMID: 35187323
Novel finding of aldehyde in 2-oxoaldehyde (2OA) is presented as it unprecedentedly disinclines to react with Grignard reagents but reacts with moderate organocuprate reagents in anaerobic condition to give [1,2]...
2.
Parmar U, Somvanshi D, Kori S, Desai A, Dandela R, Maity D, et al.
J Org Chem
. 2021 Jun;
86(13):8900-8925.
PMID: 34156851
Buchwald-Hartwig amination of chloroheteroarenes has been a challenging synthetic process, with very few protocols promoting this important transformation at ambient temperature. The current report discusses about an efficient copper-based catalytic...
3.
Gupta A, Yin X, Mukherjee M, Desai A, Mohammadlou A, Jurewicz K, et al.
Angew Chem Int Ed Engl
. 2018 Dec;
58(11):3361-3367.
PMID: 30556933
A highly diastereo- and enantioselective method for the epoxidation of aldehydes with α-diazoacetamides has been developed with two different borate ester catalysts of VANOL. Both catalytic systems are general for...
4.
Desai A, Guan Y, Odom A, Majumder S, Wulff W
Tetrahedron Lett
. 2015 Jun;
56(23):3481-3485.
PMID: 26034335
The 'template' polyborate BOROX catalysts are shown to mediate the asymmetric transfer hydrogenation of 2-quinolines. The rapid and simple generation of a large family of BOROX catalysts with significantly altered...
5.
Guan Y, Lopez-Alberca M, Lu Z, Zhang Y, Desai A, Patwardhan A, et al.
Chemistry
. 2014 Sep;
20(43):13894-900.
PMID: 25205455
Alkynyl aziridines can be obtained from the catalytic asymmetric aziridination (AZ reaction) of alkynyl imines with diazo compounds in high yields and high asymmetric inductions mediated by a chiral boroxinate...
6.
Isotope effects and mechanism of the asymmetric BOROX Brønsted acid catalyzed aziridination reaction
Vetticatt M, Desai A, Wulff W
J Org Chem
. 2013 May;
78(11):5142-52.
PMID: 23687986
The mechanism of the chiral VANOL-BOROX Brønsted acid catalyzed aziridination reaction of imines and ethyldiazoacetate has been studied using a combination of experimental kinetic isotope effects and theoretical calculations. A...
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Desai A, Wulff W
J Am Chem Soc
. 2010 Sep;
132(38):13100-3.
PMID: 20806892
Chiral polyborate based Brønsted acids prepared from the VANOL and VAPOL ligands are known to catalyze the reaction of diarylmethyl imines with diazoesters to give cis-aziridines. In the present work,...
10.
Vetticatt M, Desai A, Wulff W
J Am Chem Soc
. 2010 Sep;
132(38):13104-7.
PMID: 20806891
The stereochemistry-determining step of the self-assembled chiral Brønsted acid-catalyzed aziridination reactions of MEDAM imines and three representative diazo nucleophiles has been studied using ONIOM(B3LYP/6-31G*:AM1) calculations. The origin of cis selectivity...