Adam C Whalley
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Explore the profile of Adam C Whalley including associated specialties, affiliations and a list of published articles.
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18
Citations
334
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Recent Articles
1.
Banks P, Dyer A, Whalley A, Ruggiero M
Chem Commun (Camb)
. 2022 Oct;
58(92):12803-12806.
PMID: 36263488
The role of low-frequency (terahertz) vibrational motions on charge carrier dynamics in organic semiconductors (OSCs) is becoming well-known, and efforts are underway to rationally design new materials to mitigate these...
2.
Miller R, Averill S, Van Wyck S, Whalley A
J Org Chem
. 2016 Dec;
81(23):12001-12005.
PMID: 27934450
Functionalized derivatives of the saddle-shaped molecule tetrabenzo[8]circulene were successfully synthesized through a Diels-Alder/oxidative cyclodehydrogenation approach. This methodology improves on our previously reported synthesis, affording products containing both electron-rich and electron-poor...
3.
Sumy D, Finke A, Whalley A
Chem Commun (Camb)
. 2016 Oct;
52(83):12368-12371.
PMID: 27711278
The radical anion and dianion of tridecacyclene (CH, 1) have been prepared by reduction with potassium metal. Analysis of the solid-state structure of the dipotassium salt of the dianion (3)...
4.
Yuan B, Zhuang J, Kirmess K, Bridgmohan C, Whalley A, Wang L, et al.
J Org Chem
. 2016 Aug;
81(18):8312-8.
PMID: 27559925
We demonstrate the preparation of diacenaphthopentalene derivatives via a palladium-catalyzed dimerization of 1-iodo-2-arylethynyl-acenaphthylenes. The resulting 7,14-diarylpentaleno[1,2-a:4,5a']diacenaphthylenes, which contain four linearly fused five-membered rings, are benchtop stable and behave as hole-transporting...
5.
Sumy D, Dodge N, Harrison C, Finke A, Whalley A
Chemistry
. 2016 Jan;
22(14):4709-12.
PMID: 26791961
In this manuscript, we describe the single-step preparation of a cyclic tetramer of acenaphthylene through a Lewis acid-catalyzed aldol cyclization of 1-acenaphthenone. The previously unexplored cyclic tetramer material differs from...
6.
Avestro A, Gardner D, Vermeulen N, Wilson E, Schneebeli S, Whalley A, et al.
Angew Chem Int Ed Engl
. 2014 Mar;
53(17):4442-9.
PMID: 24623608
The controlled self-assembly of well-defined and spatially ordered π-systems has attracted considerable interest because of their potential applications in organic electronics. An important contemporary pursuit relates to the investigation of...
7.
Miller R, Duncan A, Schneebeli S, Gray D, Whalley A
Chemistry
. 2014 Mar;
20(13):3705-11.
PMID: 24615957
In 1976, the first attempted synthesis of the saddle-shaped molecule [8]circulene was reported. The next 37 years produced no advancement towards the construction of this complicated molecule. But remarkably, over...
8.
Grunder S, McGrier P, Whalley A, Boyle M, Stern C, Stoddart J
J Am Chem Soc
. 2013 Nov;
135(47):17691-4.
PMID: 24199630
A bistable donor-acceptor [2]catenane, which is composed of a crown ether containing a hydroquinone unit and a 1,5-diaminonaphthalene unit, interlocked mechanically by cyclobis(paraquat-p-phenylene) as its tetrachloride, exists as a mixture...
9.
Grunder S, Valente C, Whalley A, Sampath S, Portmann J, Botros Y, et al.
Chemistry
. 2012 Oct;
18(49):15632-49.
PMID: 23090871
Molecular gauge blocks, based on 1-7, 9-11 paraxylene rings, have been synthesized as part of a homologous series of oligoparaxylenes (OPXs) with a view to providing a molecular tool box...
10.
Ousaka N, Grunder S, Castilla A, Whalley A, Stoddart J, Nitschke J
J Am Chem Soc
. 2012 Aug;
134(37):15528-37.
PMID: 22916838
A series of large, optically active Fe(4)L(6) cages was prepared from linear 5,5'-bis(2-formylpyridines) incorporating varying numbers (n = 0-3) of oligo-p-xylene spacers, chiral amines, and Fe(II). When a cage was...