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Michael L Steigerwald

Explore the profile of Michael L Steigerwald including associated specialties, affiliations and a list of published articles. Areas
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Articles 142
Citations 1778
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Recent Articles
1.
Lee W, Prindle C, Shi W, Louie S, Steigerwald M, Venkataraman L
Nano Lett . 2025 Feb; 25(8):3316-3322. PMID: 39945435
We study single-molecule junction formation of group VIII metallocenes─ferrocene, ruthenocene, and osmocene─with gold (Au) electrodes using the scanning tunneling microscope-based break junction technique. Unlike ferrocene, both ruthenocene and osmocene can...
2.
Smith J, cavlovic D, Lackovic L, Medina Lopez M, Meirzadeh E, Steigerwald M, et al.
J Am Chem Soc . 2024 Dec; 147(1):111-117. PMID: 39715525
This manuscript describes a simple and effective method to cyclodehydrogenate arenes using liquid alkali metals. Direct reaction between molten potassium and arenes forms 6-membered rings and zigzag edged structures within...
3.
Aziz M, Prindle C, Lee W, Zhang B, Schaack C, Steigerwald M, et al.
J Phys Chem B . 2024 Sep; 128(39):9553-9560. PMID: 39317430
This study investigates the catalytic effects of external electric fields (EEFs) on two reactions in solution: the Menshutkin reaction and the Chapman rearrangement. Utilizing a scanning tunneling microscope-based break-junction (STM-BJ)...
4.
He S, Yu J, Stinson W, Looney C, Okuno S, Crowther A, et al.
J Am Chem Soc . 2024 Jul; 146(28):18861-18865. PMID: 38959425
We report an electrochemical method for doping two-dimensional (2D) superatomic semiconductor ReSeCl that significantly improves the material's electrical transport while retaining the in-plane and stacking structures. The electrochemical reduction induces...
5.
Prindle C, Shi W, Li L, Dahl Jensen J, Laursen B, Steigerwald M, et al.
J Am Chem Soc . 2024 Jan; 146(6):3646-3650. PMID: 38293735
The successful incorporation of molecules as active circuit elements relies on the ability to tune their electronic properties through chemical design. A synthetic strategy that has been used to manipulate...
6.
Bao S, Louie S, Jiang H, Jiang Q, Sun S, Steigerwald M, et al.
J Am Chem Soc . 2023 Dec; 146(1):51-56. PMID: 38110244
Here we unveil a chiral molecular redox switch derived from PDI-based twistacenes─ that has the remarkable attributes of high-intensity and a broadband chiral response. This material exhibits facile, stable, and...
7.
Xu Y, Chen J, Aydt A, Zhang L, Sergeyev I, Keeler E, et al.
Chemphyschem . 2023 Dec; 25(2):e202300064. PMID: 38057144
Molecular clusters can function as nanoscale atoms/superatoms, assembling into superatomic solids, a new class of solid-state materials with designable properties through modifications on superatoms. To explore possibilities on diversifying building...
8.
Han S, Telford E, Kundu A, Bintrim S, Turkel S, Wiscons R, et al.
Nano Lett . 2023 Nov; 23(22):10449-10457. PMID: 37934894
Two-dimensional antiferromagnets have garnered considerable interest for the next generation of functional spintronics. However, many bulk materials from which two-dimensional antiferromagnets are isolated are limited by their air sensitivity, low...
9.
Stone I, Starr R, Zang Y, Nuckolls C, Steigerwald M, Lambert T, et al.
Nat Rev Chem . 2023 Apr; 5(10):695-710. PMID: 37118183
Chemical reactions that occur at nanostructured electrodes have garnered widespread interest because of their potential applications in fields including nanotechnology, green chemistry and fundamental physical organic chemistry. Much of our...
10.
He S, Okuno S, Ng F, Pang X, Esposito D, Orchanian N, et al.
J Am Chem Soc . 2023 Apr; PMID: 37023032
We advance the chemistry of apical chlorine substitution in the 2D superatomic semiconductor ReSeCl to build functional and atomically precise monolayers on the surface of the 2D superatomic ReSe substrate....