A Novel G-CN-SH@konjac Glucomannan Composite Aerogel for Patulin Removal from Apple Juice and Its Photocatalytic Regeneration

Patulin (PAT) is a hazardous mycotoxin frequently occurs in fruit industry. A reusable g-CN-SH@KG composite aerogel for PAT removal in a novel "dark adsorption-light regeneration" mode was prepared by thiol(-SH) functionalization and konjac glucomannan (KG) immobilization. The g-CN-SH@KG was characterized by SEM, FT-IR, XPS and UV-Vis DRS, and its PAT adsorption and photocatalytic regeneration behaviors and mechanisms were investigated. The g-CN-SH@KG exhibited good regeneration performance, maintaining 83% of PAT initial adsorption capacity (0.92 mg/g) after 5 "adsorption-regeneration" cycles. The adsorption process was endothermic and spontaneous. •OH and h generated by photocatalysis were the main substances that degraded PAT into two products and regenerated -SH. The g-CN-SH@KG could effectively remove PAT without negative impact on juice quality. The study provided a new strategy for the regeneration of thiol-functionalized PAT adsorbents, and a new idea for the application of non-selective photocatalysis in the control of food contaminations.