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Intramolecular Reaction of Transient Phosphenium and Arsenium Ions Giving Rise to Isolable 9-Phospha- and 9-Arsena-Fluorenium Ions

Overview
Journal Angew Chem Int Ed Engl
Specialty Chemistry
Date 2020 May 28
PMID 32460394
Citations 4
Authors
Marian Olaru
Daniel Duvinage
Yannik Nass
Lorraine A Malaspina
Stefan Mebs
Jens Beckmann
Affiliations
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Abstract

Transient phosphenium and arsenium ions, generated by fluoride abstraction from bis(m-terphenyl)fluoropnictogens, underwent intramolecular electrophilic attack prior to methyl group migration and gave rise to isolable 9-phospha- and 9-arsena-fluorenium ions.

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Intramolecular Reaction of Transient Phosphenium and Arsenium Ions Giving Rise to Isolable 9-Phospha- and 9-Arsena-Fluorenium Ions.

Olaru M, Duvinage D, Nass Y, Malaspina L, Mebs S, Beckmann J Angew Chem Int Ed Engl. 2020; 59(34):14414-14417.

PMID: 32460394 PMC: 7496934. DOI: 10.1002/anie.202006728.

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Olaru M, Duvinage D, Nass Y, Malaspina L, Mebs S, Beckmann J . Intramolecular Reaction of Transient Phosphenium and Arsenium Ions Giving Rise to Isolable 9-Phospha- and 9-Arsena-Fluorenium Ions. Angew Chem Int Ed Engl. 2020; 59(34):14414-14417. PMC: 7496934. DOI: 10.1002/anie.202006728. View
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