Palladium-catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides

Overview

Journal J Am Chem Soc

Publisher American Chemical Society

Specialty Chemistry

Date 2010 Sep 23

PMID 20857936

Citations 24

Authors

Xiaoqiang Shen

Alan M Hyde

Stephen L Buchwald

Affiliations

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Abstract

The palladium-catalyzed conversion of aryl and vinyl triflates to aryl and vinyl halides (bromides and chlorides) has been developed using dialkylbiaryl phosphine ligands. A variety of aryl, heteroaryl, and vinyl halides can be prepared via this method in good to excellent yields.

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