Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes Under Rhodium Catalysis

Overview

Journal Chemistry

Specialty Chemistry

Date 2010 Aug 27

PMID 20740508

Citations 122

Authors

Tetsuya Satoh

Masahiro Miura

Affiliations

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Abstract

Aromatic substrates with oxygen- and nitrogen-containing substituents undergo oxidative coupling with alkynes and alkenes under rhodium catalysis through regioselective C-H bond cleavage. Coordination of the substituents to the rhodium center is the key to activate the C-H bonds effectively. Various fused-ring systems can be constructed through these reactions.

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