Iron-catalyzed Redox Radical Cyclizations of 1,6-dienes and Enynes

Overview

Journal Org Lett

Publisher American Chemical Society

Specialties Biochemistry
Chemistry

Date 2009 Dec 4

PMID 19954168

Citations 14

Authors

Tsuyoshi Taniguchi

Naoya Goto

Asami Nishibata

Hiroyuki Ishibashi

Affiliations

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Abstract

Treatment of 1,6-dienes and enynes with FeCl(3) or Fe(Pc) in the presence of NaBH(4) and air or O(2) causes radical cyclization to give five-membered carbo or heterocyclic compounds, into which a halogen atom or hydroxyl group was introduced.

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