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» Authors » Yan Z Voloshin

Yan Z Voloshin

Explore the profile of Yan Z Voloshin including associated specialties, affiliations and a list of published articles. Areas
Snapshot
Articles 47
Citations 139
Followers 0
Related Specialties
Chemistry
Biochemistry
Biology
Top 10 Co-Authors
Anna V Vologzhanina
Valentin V Novikov
Alexander S Belov
Oleg A Varzatskii
Alexander A Pavlov
Yulia V Nelyubina
Alexander V Dolganov
Genrikh E Zelinskii
Nikolay N Efimov
Yurii N Bubnov
Published In
Dalton Trans
Inorg Chem
J Phys Chem Lett
Molecules
Bioorg Med Chem Lett
Affiliations
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Recent Articles
1.
Preparation, X-ray Characterization, and Reactivity of the Rod-like and Angular Germanium- and Titanium(IV)-Capped Iron(II) Bis-Clathrochelates and Their Mono- and Bis-Capped (Semi)clathrochelate Precursors
Chuprin A, Belova S, Vologzhanina A, Dorovatovskii P, Voloshin Y
Inorg Chem . 2024 Feb; 63(9):4299-4311. PMID: 38364313
Transmetalation of the bis{triethylantimony(V)}-capped iron(II) tris-α-dioximate with -butylboronic acid afforded the mixed antimony, boron cross-linked clathrochelate with single reactive antimony(V)-based apical fragment. This macrobicyclic precursor easily underwent the transmetalation reactions...
2.
Effects of solvatomorphism, the nature of a chelating ligand synthon and a counterion on the single crystal XRD structure and SMM properties of paramagnetic monocapped cobalt(II) tris-pyrazoloximates
Belova S, Belov A, Danshina A, Zubavichus Y, Aleshin D, Pavlov A, et al.
Dalton Trans . 2023 Dec; 53(4):1482-1491. PMID: 38131298
A series of monocapped cobalt(II) tris-pyrazoloximates was obtained through the template condensation of the corresponding pyrazoloxime, phenylboronic acid and a suitable cobalt(II) halogenide. Comparing 3-acetylpyrazoloxime its methine-containing homolog, the former...
3.
Fe Mössbauer and DFT study of the electronic and spatial structures of the iron(II) (pseudo)clathrochelates: the effect of ligand field strength
Balatskiy D, Chuprin A, Dudkin S, Desdin-Garcia L, Corcho-Valdes A, Antuch M, et al.
Phys Chem Chem Phys . 2023 Jul; 25(28):18679-18690. PMID: 37403572
Combined experimental Fe Mössbauer and theoretical DFT study of a series of iron(II)-centered (pseudo)macrobicyclic analogs and homologs was performed. The field strength of the corresponding (pseudo)encapsulating ligand was found to...
4.
Multistep synthesis and X-ray structures of carboxyl-terminated hybrid iron(II) phthalocyaninatoclathrochelates and their postsynthetic transformation into polytopic carboranyl-containing derivatives
Chuprin A, Pavlov A, Vologzhanina A, Dorovatovskii P, Makarenkov A, Olshevskaya V, et al.
Dalton Trans . 2023 Mar; 52(12):3884-3895. PMID: 36877091
A multistep general synthetic strategy towards polytopic carboranyl-containing (semi)clathrochelate metal complexes, based on the template synthesis, transmetallation, amide condensation and 1,3-dipolar cycloaddition reactions, is developed. Their mono(semi)clathrochelate precursors with a...
5.
Synthesis, X-ray structure and magnetic properties of the apically functionalized monocapped cobalt(II) tris-pyridineoximates possessing SMM behaviour
Belov A, Belova S, Efimov N, Zlobina V, Novikov V, Nelyubina Y, et al.
Dalton Trans . 2023 Feb; 52(10):2928-2932. PMID: 36811361
The title cobalt(II) pseudoclathrochelate complexes possess an intermediate trigonal prismatic-trigonal antiprismatic geometry. As follows from PPMS data, they exhibit an SMM behaviour with Orbach relaxation barriers of approximately 90 K....
6.
Synthesis, crystal polymorphism and spin crossover behavior of adamantylboron-capped cobalt(II) hexachloroclathrochelate and its transformation into the CoCoCo-bis-macrobicyclic derivative
Belov A, Novikov V, Vologzhanina A, Pavlov A, Bogomyakov A, Zubavichus Y, et al.
Dalton Trans . 2022 Dec; 52(2):347-359. PMID: 36511081
Fast crystallization of the monoclathrochelate cobalt(II) intracomplex [Co(ClGm)(BAd)] (where ClGm is a dichloroglyoxime dianion and BAd is an adamantylboron capping group, 1), initially obtained by the direct template condensation of...
7.
Extension and functionalization of an encapsulating macrobicyclic ligand using palladium-catalyzed Suzuki-Miyaura and Sonogashira reactions of iron(ii) dihalogenoclathrochelates with inherent halogen substituents
Denisenko I, Varzatskii O, Selin R, Belov A, Lebed E, Vologzhanina A, et al.
RSC Adv . 2022 May; 8(24):13578-13587. PMID: 35542518
A new approach for performing Suzuki-Miyaura and Sonogashira reactions of iron(ii) dihalogenoclathrochelates, optimizing their reaction conditions (such as temperature, solvent and a palladium-containing catalyst) and the nature of other reagents...
8.
Synthesis and spectral characterization of the first fluorescein-tagged iron(ii) clathrochelates, their supramolecular interactions with globular proteins, and cellular uptake
Selin R, Klemt I, Chernii V, Losytskyy M, Chernii S, Mular A, et al.
RSC Adv . 2022 Apr; 11(14):8163-8177. PMID: 35423299
A fluorescein-tagged iron(ii) cage complex was obtained in a moderate total yield using a two-step synthetic procedure starting from its propargylamine-containing clathrochelate precursor. An 11-fold decrease in fluorescence quantum yield...
9.
Hybrid iron(II) phthalocyaninatoclathrochelates with a terminal reactive vinyl group and their organo-inorganic polymeric derivatives: synthetic approaches, X-ray structures and copolymerization with styrene
Dudkin S, Chuprin A, Belova S, Vologzhanina A, Zubavichus Y, Kaletina P, et al.
Dalton Trans . 2022 Mar; 51(14):5645-5659. PMID: 35322826
Hybrid metallo(IV)phthalocyaninate-capped tris-dioximate iron(II) complexes (termed as "phthalocyaninatoclathrochelates") with non-equivalent apical fragments and functionalized with one terminal reactive vinyl group were prepared for the first time using three different synthetic...
10.
Dramatic Effect of A Ring Size of Alicyclic α-Dioximate Ligand Synthons on Kinetics of the Template Synthesis and of the Acidic Decomposition of the Methylboron-Capped Iron(II) Clathrochelates
Pomadchik A, Belov A, Lebed E, Belaya I, Vologzhanina A, Voloshin Y
Molecules . 2021 Jul; 26(13). PMID: 34209305
Kinetics and thermodynamics of the template synthesis and of the acidic decomposition of the methylboron-capped iron(II) tris-1,2-dioximates-the clathrochelate derivatives of six (nioxime)- and eight (octoxime)-membered alicyclic ligand synthons-were compared. In...