Xiaohong Huo
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Explore the profile of Xiaohong Huo including associated specialties, affiliations and a list of published articles.
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Recent Articles
21.
Li G, Huo X, Jiang X, Zhang W
Chem Soc Rev
. 2020 Mar;
49(7):2060-2118.
PMID: 32150186
Hydrofunctionalisation and difunctionalisation of dienes, allenes, and alkynes are widely utilized in the synthesis of valuable allylic compounds. In the past decades, asymmetric catalysis has emerged as one of the...
22.
Wu Y, Huo X, Zhang W
Chemistry
. 2019 Nov;
26(22):4895-4916.
PMID: 31762085
Synergistic Pd/Cu catalysis has been utilized in the Sonogashira reaction since 1975. However, this strategy has not received much attention from the organic chemist community until recently. Synergistic Pd/Cu catalysis...
23.
Liu P, Huo X, Li B, He R, Zhang J, Wang T, et al.
Org Lett
. 2018 Oct;
20(20):6564-6568.
PMID: 30303386
The asymmetric allylation of 1-pyrroline-5-carboxylic esters has been accomplished through a synergistic Pd/Cu catalyst system under mild reaction conditions. The mechanistic studies suggested that (1) nucleophilic attack is the enantiodiscriminating...
24.
He R, Wu S, Tang H, Huo X, Sun Z, Zhang W
Org Lett
. 2018 Sep;
20(19):6183-6187.
PMID: 30240223
An iridium-catalyzed asymmetric allylation of dioxindoles, 3-hydroxyoxindoles, regulated by prosthetic groups has been accomplished under mild conditions. The methodology is applicable to a diverse array of 3-hydroxyoxindole and cinnamyl acetate...
25.
Huo X, Zhang J, Fu J, He R, Zhang W
J Am Chem Soc
. 2018 Jan;
140(6):2080-2084.
PMID: 29381351
We describe a fully stereodivergent synthesis of a range of α,α-disubstituted α-amino acids via an Ir/Cu-catalyzed α-allylation of readily available imine esters. The introduction of a Cu-Phox complex-activated imine ester...
26.
Huo X, Fu J, He X, Chen J, Xie F, Zhang W
Chem Commun (Camb)
. 2017 Dec;
54(6):599-602.
PMID: 29256570
The asymmetric allylation of glycine iminoesters has been accomplished through a synergistic Pd/Cu catalyst system, affording a range of α-substituted α-amino acids in high yields and with excellent enantioselectivities (88...
27.
Fu J, Huo X, Li B, Zhang W
Org Biomol Chem
. 2017 Nov;
15(46):9747-9759.
PMID: 29119155
Synergistic catalysis is gaining increasing attention due to its advantages over traditional catalytic methodologies, such as improved catalytic activity, broader substrate scope, increased selectivity and lower cost. Methodologies involving the...
28.
He R, Liu P, Huo X, Zhang W
Org Lett
. 2017 Oct;
19(20):5513-5516.
PMID: 28984462
A one-step enantioselective and diastereodivergent α-allylation of unprotected α-hydroxy indanones has been developed using an Ir/Zn dual catalyst system; no additional base is required. The cyclic tertiary α-hydroxyketones containing vicinal...
29.
Huo X, He R, Fu J, Zhang J, Yang G, Zhang W
J Am Chem Soc
. 2017 Jul;
139(29):9819-9822.
PMID: 28686426
We report a stereoselective and site-specific allylic alkylation of Schiff base activated amino acids and small peptides via a Pd/Cu dual catalysis. A range of noncoded α,α-dialkyl α-amino acids were...
30.
Jing J, Huo X, Shen J, Fu J, Meng Q, Zhang W
Chem Commun (Camb)
. 2017 Apr;
53(37):5151-5154.
PMID: 28439586
Allylic alcohols and allylic amines were directly utilized in a Pd-catalyzed hydrogen-bond-activated allylic amination under mild reaction conditions in the absence of any additives. The cooperative action of a Pd-catalyst...