X Peter Zhang
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Explore the profile of X Peter Zhang including associated specialties, affiliations and a list of published articles.
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94
Citations
1983
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Recent Articles
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Lee W, Zhang X
Angew Chem Int Ed Engl
. 2024 Mar;
63(20):e202320243.
PMID: 38472114
Since Friedrich Wöhler's groundbreaking synthesis of urea in 1828, organic synthesis over the past two centuries has predominantly relied on the exploration and utilization of chemical reactions rooted in two-electron...
3.
Xu H, Wang D, Zhu Z, Deb A, Zhang X
Chem
. 2024 Feb;
10(1):283-298.
PMID: 38313041
Enantioselective radical -heterobicyclization of -allylsulfamoyl azides have been developed via metalloradical catalysis (MRC). The Co(II)-based catalytic system can homolytically activate the organic azides with varied electronic and steric properties for...
4.
Lee W, Wang D, Zhu Y, Zhang X
Nat Chem
. 2023 Sep;
15(11):1569-1580.
PMID: 37679462
Metalloradical catalysis (MRC) exploits the metal-centred radicals present in open-shell metal complexes as one-electron catalysts for the generation of metal-stabilized organic radicals-key intermediates that control subsequent one-electron homolytic reactions. Cobalt(II)...
5.
Lee W, Wang J, Zhu Y, Zhang X
J Am Chem Soc
. 2023 May;
145(21):11622-11632.
PMID: 37129381
Asymmetric radical bicyclization processes have been developed via metalloradical catalysis (MRC) to stereoselectively construct chiral chromanones and chromanes bearing fused cyclopropanes. Through optimization of a versatile -symmetric chiral amidoporphyrin ligand...
6.
Lang K, Hu Y, Lee W, Zhang X
Nat Synth
. 2023 Jan;
1(7):548-557.
PMID: 36713299
Chiral amines are among the most important organic compounds and have widespread applications. Enantioselective construction of chiral amines is a major aim in organic synthesis. Among synthetic methods, direct functionalization...
7.
Xu P, Xie J, Wang D, Zhang X
Nat Chem
. 2023 Jan;
15(4):498-507.
PMID: 36635599
Although they offer great potentials, the high reactivity and diverse pathways of radical chemistry pose difficult problems for applications in organic synthesis. In addition to the differentiation of multiple competing...
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9.
Wang J, Xie J, Lee W, Wang D, Zhang X
Chem Catal
. 2022 May;
2(2):330-344.
PMID: 35494099
Diazomalonates have been demonstrated as effective metalloradicophiles for asymmetric radical olefin cyclopropanation via Co(II)-metalloradical catalysis (MRC). Supported by -symmetric chiral amidoporphyrin ligand, Co(II)-based metalloradical system can efficiently activate unsymmetrical methyl...
10.
Ke J, Lee W, Wang X, Wang Y, Wen X, Zhang X
J Am Chem Soc
. 2022 Jan;
144(5):2368-2378.
PMID: 35099966
α-Alkynyldiazomethanes, generated in situ from the corresponding sulfonyl hydrazones in the presence of a base, can serve as effective metalloradicophiles in Co(II)-based metalloradical catalysis (MRC) for asymmetric cyclopropanation of alkenes....