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Todd Schwier

Explore the profile of Todd Schwier including associated specialties, affiliations and a list of published articles. Areas
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Articles 6
Citations 94
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Recent Articles
1.
Dudnik A, Schwier T, Gevorgyan V
J Organomet Chem . 2010 Feb; 694(4):482-485. PMID: 20161695
A mild and stereoselective gold(I)-catalyzed domino transformation of propargylic esters leading to substituted (1E,3E)-dienes has been developed. This cascade process proceeds via a sequence of 1,3-acyloxy- or 1,3-phosphatyloxy migrations to...
2.
Dudnik A, Schwier T, Gevorgyan V
Org Lett . 2008 Mar; 10(7):1465-8. PMID: 18311994
A novel gold(I)-catalyzed cycloisomerization of propargylic esters leading to unsymmetrically substituted naphthalenes has been developed. This cascade reaction involves an unprecedented tandem sequence of 1,3- and 1,2-migration of two different...
3.
Schwier T, Sromek A, Yap D, Chernyak D, Gevorgyan V
J Am Chem Soc . 2007 Jul; 129(32):9868-78. PMID: 17658805
A set of cycloisomerization methodologies of alkynyl ketones and imines with concurrent acyloxy, phosphatyloxy, or sulfonyloxy group migration, which allow for the efficient synthesis of multisubstituted furans and N-fused heterocycles,...
4.
Schwier T, Gevorgyan V
Org Lett . 2005 Nov; 7(23):5191-4. PMID: 16268535
[reactions: see text] The first examples of Lewis acid catalyzed hydrogermylation of alkynes have been demonstrated. It was found that this method has much higher functional group compatibility compared to...
5.
Schwier T, Rubin M, Gevorgyan V
Org Lett . 2004 Jun; 6(12):1999-2001. PMID: 15176803
[reaction: see text] An efficient method for the B(C(6)F(5))(3)-catalyzed allylation of secondary propargylic alcohol derivatives with allylsilanes has been developed. This method allows for the facile synthesis of a variety...
6.
Rubin M, Schwier T, Gevorgyan V
J Org Chem . 2002 Mar; 67(6):1936-40. PMID: 11895414
A convenient and highly efficient method for the Lewis acid-catalyzed trans-selective hydrosilylation of alkenes has been developed. The mechanism of this novel protocol operates via direct addition of silylium type...