Sumit Sahu
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Explore the profile of Sumit Sahu including associated specialties, affiliations and a list of published articles.
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7
Citations
125
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Recent Articles
1.
Daniels C, Mendivelso-Perez D, Rosales B, You D, Sahu S, Jones J, et al.
ACS Omega
. 2019 Aug;
4(3):5197-5203.
PMID: 31459692
Intermetallics are atomically ordered crystalline compounds containing two or more main group and transition metals. In addition to their rich crystal chemistry, intermetallics display unique properties of interest for a...
2.
3.
Sahu S, Gabbai F
J Am Chem Soc
. 2017 Mar;
139(14):5035-5038.
PMID: 28345914
As part of our ongoing interest in main group species that support the photoreductive elimination of halogens, we have synthesized [ClSbPdCl(o-dppp)] (o-dppp = o-(PhP)CH), a palladium dichloride complex featuring a...
4.
Sahu S, Zhang B, Pollock C, Durr M, Davies C, Confer A, et al.
J Am Chem Soc
. 2016 Sep;
138(39):12791-12802.
PMID: 27656776
The synthesis and reactivity of a series of mononuclear nonheme iron complexes that carry out intramolecular aromatic C-F hydroxylation reactions is reported. The key intermediate prior to C-F hydroxylation, [Fe(O)(N4Py)](BF)...
5.
Sahu S, Goldberg D
J Am Chem Soc
. 2016 Aug;
138(36):11410-28.
PMID: 27576170
The rational design of well-defined, first-row transition metal complexes that can activate dioxygen has been a challenging goal for the synthetic inorganic chemist. The activation of O2 is important in...
6.
Sahu S, Quesne M, Davies C, Durr M, Ivanovic-Burmazovic I, Siegler M, et al.
J Am Chem Soc
. 2014 Sep;
136(39):13542-5.
PMID: 25246108
The synthesis of a pentadentate ligand with strategically designed fluorinated arene groups in the second coordination sphere of a nonheme iron center is reported. The oxidatively resistant fluorine substituents allow...
7.
Sahu S, Widger L, Quesne M, de Visser S, Matsumura H, Moenne-Loccoz P, et al.
J Am Chem Soc
. 2013 Jul;
135(29):10590-3.
PMID: 23834409
The new biomimetic ligands N4Py(2Ph) (1) and N4Py(2Ph,amide) (2) were synthesized and yield the iron(II) complexes [Fe(II)(N4Py(2Ph))(NCCH3)](BF4)2 (3) and [Fe(II)(N4Py(2Ph,amide))](BF4)2 (5). Controlled orientation of the Ph substituents in 3 leads...