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David P Goldberg

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Articles 123
Citations 1485
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Recent Articles
1.
Yadav V, Wen L, Yadav S, Siegler M, Goldberg D
Inorg Chem . 2024 Dec; 64(1):682-691. PMID: 39729544
The nonheme iron(II) complexes containing a fluoride anion, Fe(BNPAO)(F) () and [Fe(BNPAOH)(F)(THF)](BF) (), were synthesized and structurally characterized. Addition of dioxygen to either or led to the formation of a...
2.
Yadav S, Lyons R, Readi-Brown Z, Siegler M, Goldberg D
J Inorg Biochem . 2024 Dec; 264():112776. PMID: 39644805
The synthesis and characterization of a new ligand, 1-(bis(pyridin-2-ylmethyl) amino)-2-methylpropane-2-thiolate (BPAS) and its nonheme iron complex, Fe(BPAS)Br (1), is reported. Reaction of 1 with O at -20 °C generates a...
3.
Thomas J, Goldberg D
J Porphyr Phthalocyanines . 2024 Aug; 27(11):1489-1501. PMID: 39132380
A high-valent iron(IV)-oxo porphyrin radical cation (Fe(O)(porph) serves as a key, reactive intermediate for a range of heme enzymes, including cytochrome P450 (CYP), horseradish peroxidase (HRP), and catalase (CAT). Synthetic...
4.
Stoltzfus A, Ballot J, Vignane T, Li H, Worth M, Muller L, et al.
Angew Chem Int Ed Engl . 2024 May; 63(27):e202401003. PMID: 38808693
The gasotransmitter hydrogen sulfide (HS) is thought to be involved in the post-translational modification of cysteine residues to produce reactive persulfides. A persulfide-specific chemoselective proteomics approach with mammalian cells has...
5.
Thomas J, Mokkawes T, Senft L, Dey A, Gordon J, Ivanovic-Burmazovic I, et al.
J Am Chem Soc . 2024 Apr; 146(18):12338-12354. PMID: 38669456
The nature of the axial ligand in high-valent iron-oxo heme enzyme intermediates and related synthetic catalysts is a critical structural element for controlling proton-coupled electron-transfer (PCET) reactivity of these species....
6.
Yadav S, Yadav V, Siegler M, Moenne-Loccoz P, Jameson G, Goldberg D
J Am Chem Soc . 2024 Mar; 146(12):7915-7921. PMID: 38488295
A new alkylthiolate-ligated nonheme iron complex, Fe(BNPAS)Br (), is reported. Reaction of with O at -40 °C, or reaction of the ferric form with O at -80 °C, gives a...
7.
Yadav V, Wen L, Yadav S, Siegler M, Goldberg D
Inorg Chem . 2023 Oct; 62(43):17830-17842. PMID: 37857315
A series of nonheme iron complexes, Fe(BNPAO)(L)(L) (L = N, NCS, NCO, and Cl) have been synthesized using the previously reported BNPAO ligand. The ferrous analogs Fe(BNPAO)(L) (L = N,...
8.
Spentzos A, May S, Confer A, Gau M, Carroll P, Goldberg D, et al.
Inorg Chem . 2023 Jul; 62(29):11487-11499. PMID: 37428000
This article describes the synthesis, characterization, and S-atom transfer reactivity of a series of -symmetric diiron complexes. The iron centers in each complex are coordinated in distinct ligand environments, with...
9.
Gordon J, Albert T, Dey A, Sabuncu S, Siegler M, Bill E, et al.
J Am Chem Soc . 2023 May; 145(20):11466. PMID: 37167479
No abstract available.
10.
Gordon J, Albert T, Yadav S, Thomas J, Siegler M, Moenne-Loccoz P, et al.
Inorg Chem . 2022 Dec; 62(1):392-400. PMID: 36538786
A five-coordinate, disiloxide-ligated cobalt(II) ( = 3/2) complex () was prepared as an oxygen-ligated analogue to the previously reported silanedithiolate-ligated Co(MeTACN)(SSiMe) ( , , 3641-3653). The structural and spectroscopic properties...