Shyam Sathyamoorthi
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Explore the profile of Shyam Sathyamoorthi including associated specialties, affiliations and a list of published articles.
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42
Citations
367
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Recent Articles
1.
Sathyamoorthi S, Kelley S
Med Chem Res
. 2024 Dec;
33:1423-1431.
PMID: 39669980
We have developed convenient protocols for alkene disulfonoxylation, which involve stirring alkene substrate with a commercial I(III) oxidant and sulfonic acid in CHCl at ambient temperature. The reactions can be...
2.
Joshi H, Manna A, Nagamalla S, Thomas A, Sathyamoorthi S
Org Lett
. 2024 Dec;
26(50):10708-10713.
PMID: 39660506
We show the first examples of enantioselective cyclization reactions of tethered sulfamates onto pendant α,β-unsaturated esters, ketones, and thioesters. This reaction is promoted by a new chiral bifunctional guanidine catalyst...
3.
Nirpal A, Joshi H, Kelley S, Sathyamoorthi S
J Org Chem
. 2024 Nov;
89(22):16774-16778.
PMID: 39492674
We show the first examples of one-pot tandem sulfamoylation/-Michael reactions for the preparation of oxathiazinane dioxide heterocycles from linear alkenyl alcohol precursors. Our optimized protocols are tolerant of a variety...
4.
Silver R, Nirpal A, Sathyamoorthi S
J Org Chem
. 2024 Oct;
89(20):15352-15357.
PMID: 39387609
We present the first examples of amino-trifluoroacetoxylations of alkenes using -alkoxy carbamate tethers. Hypervalent iodine oxidants mediate this transformation, providing a "green" alternative to existing intramolecular amino-hydroxylation protocols which use...
5.
Sathyamoorthi S
European J Org Chem
. 2024 Sep;
27(9).
PMID: 39309710
Compared to ubiquitous functional groups such as alcohols, carboxylic acids, amines, and amides, which serve as central "actors" in most organic reactions, sulfamates, phosphoramidates, and di--butyl silanols have historically been...
6.
Joshi H, Sathyamoorthi S
J Org Chem
. 2024 Sep;
89(19):14197-14203.
PMID: 39305247
We present the first racemic and scalemic examples of di--butyl silanoxy-Michael additions. Our operationally simple protocol is selective for nitro-olefins and simply involves stirring the substrate with an appropriate hydrogen-bond...
7.
Mandal G, Kelley S, Sathyamoorthi S
Org Lett
. 2024 Jun;
26(26):5463-5466.
PMID: 38904476
Here, we present the first enantioselective total syntheses of the natural products (+)-kasugamycin, a potent antifungal antibiotic, and (+)-kasuganobiosamine, a compound that results from the degradation of kasugamycin. Salient features...
8.
Joshi H, Nirpal A, Paul D, Kelley S, Mague J, Sathyamoorthi S
J Org Chem
. 2024 Apr;
89(8):5911-5916.
PMID: 38597462
We present the first examples of intramolecular aza-Michael cyclizations of sulfamates and sulfamides onto pendant α,β-unsaturated esters, thioesters, amides, and nitriles. Stirring the substrate with catalytic quantities of the appropriate...
9.
Thomas A, Nagamalla S, Sathyamoorthi S
Organic Synth
. 2024 Jan;
100:446-468.
PMID: 38274130
No abstract available.
10.
Mandal G, Sathyamoorthi S
J Org Chem
. 2023 Dec;
89(1):793-797.
PMID: 38062940
We present our preparation of a kasugamine synthon, which proceeds in 14 steps from a literature epoxide. We expect that this kasugamine derivative can be used for the total syntheses...