Shih-Yuan Liu
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Explore the profile of Shih-Yuan Liu including associated specialties, affiliations and a list of published articles.
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92
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1062
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Recent Articles
1.
Lin H, Yang X, Liu S, Jakle F
ACS Macro Lett
. 2024 Aug;
13(8):1093.
PMID: 39115083
No abstract available.
2.
Ozaki T, Bentley S, Rybansky N, Li B, Liu S
J Am Chem Soc
. 2024 Jul;
146(36):24748-24753.
PMID: 39082667
The synthesis and crystallographic characterization of BN-benzvalene, the first second-row heteroatom-containing benzvalene, is described. BN-benzvalenes are produced via photoexcitation of C5-aryl-substituted 1,2-azaborines under flow conditions. Mechanistic studies support a boron-specific,...
3.
Ozaki T, Liu S
Chemistry
. 2024 Jul;
30(55):e202402544.
PMID: 39056374
Benzene is one of the most ubiquitous structural motifs in chemistry. The valence isomers of benzene have also attracted synthetic chemists' attention due to their unique structures, bonding, and reactivity....
4.
Lee H, Alvarado M, Ingram S, Li B, Liu S
Synlett
. 2024 Jul;
34(18):2169-2174.
PMID: 39006063
General protocols for the N-functionalization of 1,2-azaborines with C(sp), C(sp), or C(sp) electrophiles are described. The syntheses of a new parental BN isostere of -stilbene and a BN isostere of...
5.
Eaton M, Zhang Y, Liu S
Chem Soc Rev
. 2024 Jan;
53(4):1915-1935.
PMID: 38190152
Borataalkenes and boraalkenes are the boron-containing isoelectronic analogues of alkenes and vinyl cations respectively. Compared with alkenes, the borataalkene and boraalkene ligand motifs in transition metal coordination chemistry are relatively...
6.
Lin H, Yang X, Liu S, Jakle F
ACS Macro Lett
. 2023 Dec;
13(1):21-27.
PMID: 38095183
The successful polymerization of the Dewar isomer of an azaborinine heterocycle is reported. Controlled ring-opening metathesis polymerization was accomplished with Grubbs and Hoveya-Grubbs second generation catalysts (G2, HG2), as well...
7.
Eaton M, Dai Y, Wang Z, Li B, Lamine W, Miqueu K, et al.
J Am Chem Soc
. 2023 Sep;
145(39):21638-21645.
PMID: 37738372
A method for the synthesis of allenes by the addition of ketones to 1,3-enynes by cooperative Pd(0)Senphos/B(CF)/NR catalysis is described. A wide range of aryl- and aliphatic ketones undergo addition...
8.
Robichaud H, Ishibashi J, Ozaki T, Lamine W, Miqueu K, Liu S
Org Biomol Chem
. 2023 Apr;
21(18):3778-3783.
PMID: 37092259
The first aromatic Claisen rearrangement of a 1,2-azaborine is described along with a quantitative kinetic comparison of the reaction of the azaborine with its direct all-carbon analogue. The azaborine A...
9.
Wang Z, Zhang C, Wu J, Li B, Chrostowska A, Karamanis P, et al.
J Am Chem Soc
. 2023 Mar;
145(10):5624-5630.
PMID: 36862947
A cooperative catalyst system involving a Pd(0)/Senphos complex, tris(pentafluorophenyl)borane, copper bromide, and an amine base, is demonstrated to catalyze -hydroalkynylation of internal 1,3-enynes. For the first time, a Lewis acid...
10.
Wang Z, Lamine W, Miqueu K, Liu S
Chem Sci
. 2023 Feb;
14(8):2082-2090.
PMID: 36845936
We report a combined experimental and computational study of Pd/Senphos-catalyzed carboboration of 1,3-enynes utilizing DFT calculations, P NMR study, kinetic study, Hammett analysis and Arrhenius/Eyring analysis. Our mechanistic study provides...