Sebastian Sobottka
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Explore the profile of Sebastian Sobottka including associated specialties, affiliations and a list of published articles.
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29
Citations
172
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Recent Articles
1.
Wasternack J, Schroder H, Witte J, Ilisson M, Hupatz H, Hille J, et al.
Commun Chem
. 2024 Oct;
7(1):229.
PMID: 39367250
In nature, molecular environments in proteins can sterically protect and stabilize reactive species such as organic radicals through non-covalent interactions. Here, we report a near-infrared fluorescent rotaxane in which the...
2.
Maiti A, Sobottka S, Chandra S, Jana D, Ravat P, Sarkar B, et al.
J Org Chem
. 2021 Nov;
86(23):16464-16472.
PMID: 34780693
Herein, we report diamidocarbene (DAC)-based Thiele and Tschitschibabin hydrocarbons, diradicaloids that contain four carbonyl/amido functional groups. The impact of two different π-conjugated spacers, -phenylene vs ,'-biphenylene, has been realized. The...
3.
Beerhues J, Neubrand M, Sobottka S, Neuman N, Aberhan H, Chandra S, et al.
Chemistry
. 2021 Jan;
27(21):6557-6568.
PMID: 33502818
Carbene-based radicals are important for both fundamental and applied chemical research. Herein, extensive electrochemical investigations of nine different 1,2,3-triazolylidene selenium adducts are reported. It is found that the half-wave potentials...
4.
Ludtke C, Sobottka S, Heinrich J, Liebing P, Wedepohl S, Sarkar B, et al.
Chemistry
. 2020 Nov;
27(10):3273-3277.
PMID: 33245157
[Cu(phen) ] (phen=1,10-phenanthroline) is the first and still one of the most efficient artificial nucleases. In general, when the phen ligand is modified, the nucleolytic activity of its Cu complex...
5.
Bens T, Boden P, Di Martino-Fumo P, Beerhues J, Albold U, Sobottka S, et al.
Inorg Chem
. 2020 Oct;
59(20):15504-15513.
PMID: 33021374
This work reports on the synthesis and in-depth electrochemical and photochemical characterization of two chromium(0) and molydenum(0) metal complexes with bidentate pyridyl-mesoionic carbene (MIC) ligands of the 1,2,3-triazol-5-ylidene type and...
6.
Rietsch P, Sobottka S, Hoffmann K, Popov A, Hildebrandt P, Sarkar B, et al.
Chemistry
. 2020 Sep;
26(72):17361-17365.
PMID: 32997430
Reversibly switching the light absorption of organic molecules by redox processes is of interest for applications in sensors, light harvesting, smart materials, and medical diagnostics. This work presents a symmetrical...
7.
Jia F, Schroder H, Yang L, von Essen C, Sobottka S, Sarkar B, et al.
J Am Chem Soc
. 2020 Feb;
142(7):3306-3310.
PMID: 32013425
"Naphthocage", a naphthalene-based organic cage, reveals very strong binding (up to 10 M) to aromatic (di)cationic guests, i.e., the tetrathiafulvalene mono- and dication and methyl viologen. Intercalation of the guests...
8.
Sobottka S, Nossler M, Ostericher A, Hermann G, Subat N, Beerhues J, et al.
Chemistry
. 2019 Nov;
26(6):1314-1327.
PMID: 31778594
Asymmetric platinum donor-acceptor complexes [(pimp)Pt(Q )] are presented in this work, in which pimp=[(2,4,6-trimethylphenylimino)methyl]pyridine and Q =catecholate-type donor ligands. The properties of the complexes are evaluated as a function of...
9.
Sobottka S, van der Meer M, Glais E, Albold U, Suhr S, Su C, et al.
Dalton Trans
. 2019 Jul;
48(37):13931-13942.
PMID: 31314025
Redox-active ligands, owing to their electron reservoir capability, are well suited for the generation of coordinatively unsaturated metal complexes. We present here iridium complexes with an unsymmetrically substituted o-phenylenediamine ligand....
10.
Khan F, Sobottka S, Sarkar B, Lahiri G
Chemistry
. 2019 May;
25(41):9737-9746.
PMID: 31125467
In the recent years, there has been an emerging research interest in the domain of C-C bond-cleavage reactions. The present contribution deals with the redox-mediated dioxygen activation and C-C bond...