Scott L Cockroft
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Explore the profile of Scott L Cockroft including associated specialties, affiliations and a list of published articles.
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55
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1223
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Recent Articles
1.
Elmi A, Bak K, Cockroft S
Angew Chem Int Ed Engl
. 2024 Jul;
63(45):e202412056.
PMID: 39041859
Solvent competition for London dispersion attenuates its energetic significance in molecular recognition processes. By varying both the stacked contact area and the solvent, here we experimentally deconvolute solvent attenuation using...
2.
van Teijlingen A, Edwards D, Hu L, Lilienkampf A, Cockroft S, Tuttle T
Phys Chem Chem Phys
. 2024 Jun;
26(25):17745-17752.
PMID: 38873737
Membrane-disrupting and pore-forming peptides (PFPs) play a substantial role in bionanotechnology and can determine the life and death of cells. The control of chemical and ion transport through cell membranes...
3.
Gravillier L, Cockroft S
Acc Chem Res
. 2023 Nov;
56(23):3535-3544.
PMID: 37994023
ConspectusLondon forces constitute an attractive component of van der Waals interactions and originate from transient correlated momentary dipoles in adjacent atoms. The in-depth investigation of London dispersion forces poses notable...
4.
West A, Dominelli-Whiteley N, Smolyar I, Nichol G, Cockroft S
Angew Chem Int Ed Engl
. 2023 Jul;
62(38):e202309682.
PMID: 37470309
Crystallographic and computational studies suggest the occurrence of favourable interactions between polarizable arenes and halogen atoms. However, the systematic experimental quantification of halogen⋅⋅⋅arene interactions in solution has been hindered by...
5.
Meredith N, Borsley S, Smolyar I, Nichol G, Baker C, Ling K, et al.
Angew Chem Int Ed Engl
. 2022 May;
61(30):e202206604.
PMID: 35608961
The experimental isolation of H-bond energetics from the typically dominant influence of the solvent remains challenging. Here we use synthetic molecular balances to quantify amine/amide H-bonds in competitive solvents. Over...
6.
Cairns-Gibson D, Cockroft S
Chem Sci
. 2022 Mar;
13(7):1869-1882.
PMID: 35308845
Nanopore technology has established itself as a powerful tool for single-molecule studies. By analysing changes in the ion current flowing through a single transmembrane channel, a wealth of molecular information...
7.
Elmi A, Cockroft S
Acc Chem Res
. 2020 Dec;
54(1):92-103.
PMID: 33315374
Where the basic units of molecular chemistry are the bonds molecules, supramolecular chemistry is based on the interactions that occur molecules. Understanding the "how" and "why" of the processes that...
8.
Zheng Q, Borsley S, Tu T, Cockroft S
Chem Commun (Camb)
. 2020 Nov;
56(93):14705-14708.
PMID: 33170199
We report the reversible chromism and luminescence of a cyclometalated platinum(ii) complex that forms dimers, with close PtPt interactions that can be modulated by solvent and temperature. The precise reversible...
9.
August D, Borsley S, Cockroft S, Della Sala F, Leigh D, Webb S
J Am Chem Soc
. 2020 Oct;
142(44):18859-18865.
PMID: 33084320
A (Fe)-coordinated triply interlocked ("Star of David") [2]catenane (6 link) and a (Fe)-coordinated pentafoil (5) knot are found to selectively transport anions across phospholipid bilayers. Allostery, topology, and building block...
10.
Falconer R, Nichol G, Smolyar I, Cockroft S, Cowley M
Angew Chem Int Ed Engl
. 2020 Oct;
60(4):2047-2052.
PMID: 33022874
Oxidative addition and reductive elimination are defining reactions of transition-metal organometallic chemistry. In main-group chemistry, oxidative addition is now well-established but reductive elimination reactions are not yet general in the...