Robert G Bergman
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Explore the profile of Robert G Bergman including associated specialties, affiliations and a list of published articles.
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250
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3647
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Recent Articles
1.
Treacy S, Smith A, Bergman R, Raymond K, Toste F
J Am Chem Soc
. 2024 Oct;
146(43):29792-29800.
PMID: 39432827
Catalysis of multicomponent transformations requires controlled assembly of reactants within the active site. Supramolecular scaffolds possess synthetic microenvironments that enable precise modulation over noncovalent interactions (NCIs) engaged by reactive, encapsulated...
2.
Brackbill I, Rajeshkumar T, Douair I, Maron L, Boreen M, Bergman R, et al.
J Am Chem Soc
. 2024 Jul;
146(31):21932-21947.
PMID: 39051942
The electronic organization of Frustrated Lewis Pairs (FLPs) allows them to activate strong bonds in mechanisms that are usually free of redox events at the Lewis acidic site. The unique...
3.
Hales D, Rajeshkumar T, Shiau A, Rao G, Ouellette E, Bergman R, et al.
Inorg Chem
. 2024 Jun;
63(24):11296-11310.
PMID: 38836624
We expand upon the synthetic utility of anionic rhenium complex Na[(BDI)ReCp] (, BDI = -bis(2,6-diisopropylphenyl)-3,5-dimethyl-β-diketiminate) to generate several rhenium-phosphorus complexes. Complex reacts in a metathetical manner with chlorophosphines PhPCl, NHP-Cl,...
4.
Ouellette E, Brackbill I, Kynman A, Christodoulou S, Maron L, Bergman R, et al.
Inorg Chem
. 2024 Apr;
63(16):7177-7188.
PMID: 38598523
While synthesizing a series of rhenium-lanthanide triple inverse sandwich complexes, we unexpectedly uncovered evidence for rare examples of end-on lanthanide dinitrogen coordination for certain heavy lanthanide elements as well as...
5.
Brackbill I, Rajeshkumar T, Maron L, Bergman R, Arnold J
J Am Chem Soc
. 2024 Jan;
146(2):1257-1261.
PMID: 38189272
Dihydrogen complexation, a phenomenon with robust precedent in the transition metal series, is spectroscopically detected for a uranium(III) complex and thereby extended for the first time to the 5f series....
6.
Xia K, Rajan A, Surendranath Y, Bergman R, Raymond K, Toste F
J Am Chem Soc
. 2023 Nov;
145(46):25463-25470.
PMID: 37956314
An aqueous electrochemically controlled host-guest encapsulation system demonstrates a large and synthetically tunable redox entropy change. Electrochemical entropy is the basis for thermally regenerative electrochemical cycles (TRECs), which utilize reversible...
7.
Ouellette E, Magdalenski J, Bergman R, Arnold J
Inorg Chem
. 2022 Sep;
61(40):16064-16071.
PMID: 36150135
We report the synthesis and characterization of rhenium-group 9 heterobimetallic diazenido species (η-Cp)Re(μ-BDI)(μ-N)M(η-COD) (, M = Ir or Rh, Cp = cyclopentadienide, BDI = ,'-bis(2,6-diisopropylphenyl)-3,5-dimethyl-β-diketiminate, COD = 1,5-cyclooctadiene), formed from...
8.
Fostvedt J, Mendoza J, Lopez-Flores S, Alcantar D, Bergman R, Arnold J
Chem Sci
. 2022 Aug;
13(28):8224-8242.
PMID: 35919706
In this Perspective, we discuss the strategy of π-loading, , coordination of two or more strongly π-donating ligands to a single metal center, as it applies to promoting reactivity at...
9.
Bierschenk S, Pan J, Settineri N, Warzok U, Bergman R, Raymond K, et al.
J Am Chem Soc
. 2022 Jun;
144(25):11425-11433.
PMID: 35700232
A highly enantioselective aza-Darzens reaction (up to 99% ee) catalyzed by an enantiopure supramolecular host has been discovered. To understand the role of host structure on reaction outcome, nine new...
10.
Nguyen Q, Xia K, Zhang Y, Chen N, Morimoto M, Pei X, et al.
J Am Chem Soc
. 2022 Jun;
144(25):11413-11424.
PMID: 35699585
The results of quantum chemical and molecular dynamics calculations reveal that polyanionic gallium-based cages accelerate cyclization reactions of pentadienyl alcohols as a result of substrate cage interactions, preferential binding of...