Rene T Boere

The synthesis and extensive characterization of nine aryl sulfur diimides (SDIs, Ar-NSN-Ar) are presented with a robust computational and experimental investigation of the fundamental properties of these important members of...

The single-crystal X-ray diffraction structure characterizing a new 4-methylbenzamidinium salt of chloroselenite [CHN][ClSeO] is reported. This is only the second crystal structure report on a ClSeO salt. The structure contains...

We describe nonmetal adducts of the phosphorus center of terminal phosphinidene complexes using classical C- and N-ligands from metal coordination chemistry. The nature of the L-P bond has been analyzed...

Phospha-Wittig reagents such as phosphanylidene-phosphoranes and their transition metal complexes are of great interest as sources of P building blocks but the access is still limited. Herein, we describe a...

P-Functional phosphanylated tetrathiafulvalenes 3a-f were synthesised stepwise lithiation and phosphanylation of TTF derivatives, and then reacted with PCl to form the related -chloro compounds 4a-f. Reactions of 4c-f with LDA...

Tricyclic 1,4-dihydro-1,4-phosphasilines 3a,b were synthesized from Si(NR)-bridged imidazole-2-thione compounds 2a,b. Based on calculated FMOs of 3b, forecasting a possible P-selective P-N bond cleavage reduction, a redox cycle could be established...

Fourteen crystal structures, mostly from good-quality datasets but including some marginal and twinned exemplars, from a series of novel polycyclic benzo- and naphtho-fused organic nitriles are presented and accurately described,...

Anionic 1,4-dihydro-1,4-diphosphinines were synthesized from tricyclic 1,4-diphosphinines and isolated as blue powdery salts M[-]. Reaction of solutions of these monoanions with iodomethane led to -methylated compounds -. An oxidation/reduction cycle...

The compound bis-{μ-2,5-bis-[-(4-iso-propyl-phen-yl)-,-di-phenyl-phospho-r-im-i-do-yl]pyrrol-1-ido-κ :':''}tris-ilver(I) tri-fluoro-methane-sulfonate deuterated benzene penta-solvate, [Ag(CHNP)](CFOS)·5CD, (I), was synthesized from two equivalents of Na [ = 2,5-(4- PrCHN=PPh)CHN] and three equivalents of AgOTf (OTf = OSOCF). High-quality...

The Lewis acid-base adducts MoF(NCH) and MoOF(NCH) ( = 1, 2) were synthesized from the reactions of MoF and MoOF with CHN and structurally characterized by X-ray crystallography. Whereas the...