Rebecca A M Randall
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Explore the profile of Rebecca A M Randall including associated specialties, affiliations and a list of published articles.
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11
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Recent Articles
1.
Knight F, Diamond L, Athukorala Arachchige K, Sanz Camacho P, Randall R, Ashbrook S, et al.
Chemistry
. 2014 Dec;
21(9):3613-27.
PMID: 25533475
Three related series of peri-substituted bis(tellurides) bearing naphthalene, acenaphthene and acenaphthylene backbones (Nap/Acenap/Aceyl(TeY)2 (Nap = naphthalene-1,8-diyl N; Acenap = acenaphthene-5,6-diyl A; Aceyl = acenaphthylene-5,6-diyl Ay; Y = Ph 1; Fp...
2.
Knight F, Randall R, Roemmele T, Boere R, Bode B, Crawford L, et al.
Chemphyschem
. 2013 Aug;
14(14):3199-203.
PMID: 23943606
Chalcogen dications: Facile synthesis of E--E bonded dications can be readily achieved. Radical cations are identified as the intermediates.
3.
Ray M, Randall R, Athukorala Arachchige K, Slawin A, Buhl M, Lebl T, et al.
Inorg Chem
. 2013 Mar;
52(8):4346-59.
PMID: 23534381
Coupling of two acenaphthene backbones through a phosphorus atom in a geminal fashion gives the first geminally bis(peri-substituted) tridentate phosphine 1. The rigid nature of the aromatic backbone and overall...
4.
Hua G, Slawin A, Randall R, Cordes D, Crawford L, Buhl M, et al.
Chem Commun (Camb)
. 2013 Feb;
49(26):2619-2621.
PMID: 23436007
Four-membered ring [PhP(Se)(μ-Se)]2 (Woollins' reagent, WR) reacts with disodium alkenyl-diols followed by in situ ring-closure reaction with appropriate dibromoalkanes affording a series of unusual nine- to fifteen-membered organoselenophosphorus macrocycles bearing...
5.
Buhl M, Knight F, Kristkova A, Ondik I, Malkina O, Randall R, et al.
Angew Chem Int Ed Engl
. 2013 Jan;
52(9):2495-8.
PMID: 23345140
Across the bay: J((125)Te, (125)Te) spin-spin coupling is a highly sensitive probe into the electronic and geometric structure of 1,8-peri-substituted naphthalene tellurium derivatives. The coupling is related to the onset...
6.
Knight F, Randall R, Wakefield L, Slawin A, Woollins J
Molecules
. 2012 Nov;
17(11):13307-29.
PMID: 23138535
Six silver(I) coordination complexes have been prepared and structurally characterised. Mixed chalcogen-donor acenaphthene ligands L1-L3 [Acenap(EPh)(E'Ph)] (Acenap = acenaphthene-5,6-diyl; E/E' = S, Se, Te) were independently treated with silver(I) salts...
7.
Knight F, Randall R, Wakefield L, Slawin A, Woollins J
Dalton Trans
. 2012 Oct;
42(1):143-54.
PMID: 23108191
Six related organo–chalconium silver(I) coordination complexes, including two examples of rare organotellurium-silver coordination, have been prepared and structurally characterised by X-ray crystallography. The series of 5-bromo-6-(phenylchalcogeno)acenaphthene ligands L1–L3 [Acenap(Br)(EPh)] (Acenap...
8.
Knight F, Randall R, Athukorala Arachchige K, Wakefield L, Griffin J, Ashbrook S, et al.
Inorg Chem
. 2012 Sep;
51(20):11087-97.
PMID: 23004571
Twelve related monocation chalconium salts [{Nap(EPh)(E'Ph)Me}(+){CF(3)SO(3)}(-)] 2-4, [{Acenap(Br)(EPh)Me}{CF(3)SO(3)}(-)] 5-7, and [{Acenap(EPh)(E'Ph)Me}(+){CF(3)SO(3)}(-)] 8-13 have been prepared and structurally characterized. For their synthesis naphthalene compounds [Nap(EPh)(E'Ph)] (Nap = naphthalene-1,8-diyl; E/E' = S,...
9.
Knight F, Athukorala Arachchige K, Randall R, Buhl M, Slawin A, Woollins J
Dalton Trans
. 2012 Feb;
41(11):3154-65.
PMID: 22290272
Sterically crowded peri-substituted selenium and tellurium acenaphthene donors D1-D7 [Acenap(EPh)(Br) E = Se, Te; Acenap(SePh)(EPh) E = Se, S; Acenap(TePh)(EPh) E = S, Se, Te] react with dibromine and diiodine...
10.
Aschenbach L, Knight F, Randall R, Cordes D, Baggott A, Buhl M, et al.
Dalton Trans
. 2011 Dec;
41(11):3141-53.
PMID: 22175061
Two series of sterically crowded peri-substituted acenaphthenes have been prepared, containing mixed halogen-chalcogen functionalities at the 5,6-positions in A1-A6 (Acenap[X][EPh] (Acenap = acenaphthene-5,6-diyl; X = Br, I; E = S,...