Fergus R Knight
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Explore the profile of Fergus R Knight including associated specialties, affiliations and a list of published articles.
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19
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81
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Recent Articles
1.
Braunschweig H, Constantinidis P, Dellermann T, Ewing W, Fischer I, Hess M, et al.
Angew Chem Int Ed Engl
. 2016 Mar;
55(18):5606-9.
PMID: 27027522
The reactions of a diborene with elemental selenium or tellurium are shown to afford a diboraselenirane or diboratellurirane, respectively. These reactions are reminiscent of the sequestration of subvalent oxygen and...
2.
Nordheider A, Hupf E, Chalmers B, Knight F, Buhl M, Mebs S, et al.
Inorg Chem
. 2015 Feb;
54(5):2435-46.
PMID: 25692668
A series of peri-substituted phosphorus-tellurium systems R'Te-Acenap-PR2 (R' = Ph, p-An, Nap, Mes, Tip; Acenap = acenaphthene-5,6-diyl (-C12H8); R = (i)Pr, Ph) exhibiting large "through-space" spin-spin coupling constants and the...
3.
Knight F, Diamond L, Athukorala Arachchige K, Sanz Camacho P, Randall R, Ashbrook S, et al.
Chemistry
. 2014 Dec;
21(9):3613-27.
PMID: 25533475
Three related series of peri-substituted bis(tellurides) bearing naphthalene, acenaphthene and acenaphthylene backbones (Nap/Acenap/Aceyl(TeY)2 (Nap = naphthalene-1,8-diyl N; Acenap = acenaphthene-5,6-diyl A; Aceyl = acenaphthylene-5,6-diyl Ay; Y = Ph 1; Fp...
4.
Chalmers B, Athukorala Arachchige K, Prentis J, Knight F, Kilian P, Slawin A, et al.
Inorg Chem
. 2014 Aug;
53(16):8795-808.
PMID: 25080308
A group of sterically encumbered peri-substituted acenaphthenes have been prepared, containing tin moieties at the 5,6-positions in 1-3 ([Acenap(SnR3)2], Acenap = acenaphthene-5,6-diyl; R3 = Ph3 (1), Me3 (2); [(Acenap)2(SnMe2)2] (3))...
5.
Stanford M, Knight F, Athukorala Arachchige K, Sanz Camacho P, Ashbrook S, Buhl M, et al.
Dalton Trans
. 2014 Mar;
43(17):6548-60.
PMID: 24623141
The series of eight 5-(TeY)-6-(SePh)acenaphthenes (Y = Fp (2), Tol (3), An-p (4), An-o (5), Tp (6), Mes (7), Tip (8), Nap (9)) were prepared and structurally characterised by X-ray...
6.
Knight F, Randall R, Roemmele T, Boere R, Bode B, Crawford L, et al.
Chemphyschem
. 2013 Aug;
14(14):3199-203.
PMID: 23943606
Chalcogen dications: Facile synthesis of E--E bonded dications can be readily achieved. Radical cations are identified as the intermediates.
7.
Buhl M, Knight F, Kristkova A, Ondik I, Malkina O, Randall R, et al.
Angew Chem Int Ed Engl
. 2013 Jan;
52(9):2495-8.
PMID: 23345140
Across the bay: J((125)Te, (125)Te) spin-spin coupling is a highly sensitive probe into the electronic and geometric structure of 1,8-peri-substituted naphthalene tellurium derivatives. The coupling is related to the onset...
8.
Knight F, Randall R, Wakefield L, Slawin A, Woollins J
Molecules
. 2012 Nov;
17(11):13307-29.
PMID: 23138535
Six silver(I) coordination complexes have been prepared and structurally characterised. Mixed chalcogen-donor acenaphthene ligands L1-L3 [Acenap(EPh)(E'Ph)] (Acenap = acenaphthene-5,6-diyl; E/E' = S, Se, Te) were independently treated with silver(I) salts...
9.
Knight F, Randall R, Wakefield L, Slawin A, Woollins J
Dalton Trans
. 2012 Oct;
42(1):143-54.
PMID: 23108191
Six related organo–chalconium silver(I) coordination complexes, including two examples of rare organotellurium-silver coordination, have been prepared and structurally characterised by X-ray crystallography. The series of 5-bromo-6-(phenylchalcogeno)acenaphthene ligands L1–L3 [Acenap(Br)(EPh)] (Acenap...
10.
Knight F, Randall R, Athukorala Arachchige K, Wakefield L, Griffin J, Ashbrook S, et al.
Inorg Chem
. 2012 Sep;
51(20):11087-97.
PMID: 23004571
Twelve related monocation chalconium salts [{Nap(EPh)(E'Ph)Me}(+){CF(3)SO(3)}(-)] 2-4, [{Acenap(Br)(EPh)Me}{CF(3)SO(3)}(-)] 5-7, and [{Acenap(EPh)(E'Ph)Me}(+){CF(3)SO(3)}(-)] 8-13 have been prepared and structurally characterized. For their synthesis naphthalene compounds [Nap(EPh)(E'Ph)] (Nap = naphthalene-1,8-diyl; E/E' = S,...