Paul L Alsters
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Explore the profile of Paul L Alsters including associated specialties, affiliations and a list of published articles.
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Recent Articles
1.
van Slagmaat C, Faber T, Chou K, Schwalb Freire A, Hadavi D, Han P, et al.
Dalton Trans
. 2021 Jul;
50(29):10102-10112.
PMID: 34240727
The hydrogenative conversions of the biobased platform molecules 4-hydroxycyclopent-2-enone and cyclopentane-1,3-dione to their corresponding 1,3-diols are established using a pre-activated Knölker-type iron catalyst. The catalyst exhibits a high selectivity for...
2.
van Slagmaat C, Verzijl G, Quaedflieg P, Alsters P, De Wildeman S
ACS Omega
. 2021 Feb;
6(6):4313-4328.
PMID: 33623842
Cyclopentane-1,3-diol () has gained renewed attention as a potential building block for polymers and fuels because its synthesis from hemicellulose-derived 4-hydroxycyclopent-2-enone () was recently disclosed. However, cyclopentane-1,3-dione (), which is...
3.
Dong J, Fananas-Mastral M, Alsters P, Browne W, Feringa B
Angew Chem Int Ed Engl
. 2013 Apr;
52(21):5561-5.
PMID: 23592559
No abstract available.
4.
Pijper D, Saisaha P, de Boer J, Hoen R, Smit C, Meetsma A, et al.
Dalton Trans
. 2010 Oct;
39(43):10375-81.
PMID: 20886164
A number of manganese-based catalysts employing ligands whose structures incorporate pyridyl groups have been reported previously to achieve both high turnover numbers and selectivity in the oxidation of alkenes and...
5.
Saisaha P, Pijper D, van Summeren R, Hoen R, Smit C, de Boer J, et al.
Org Biomol Chem
. 2010 Aug;
8(19):4444-50.
PMID: 20714666
A practical method for the multigram scale selective cis-dihydroxylation of electron deficient alkenes such as diethyl fumarate and N-alkyl and N-aryl-maleimides using H(2)O(2) is described. High turnovers (>1000) can be...
6.
Kilic H, Adam W, Alsters P
J Org Chem
. 2009 Jan;
74(3):1135-40.
PMID: 19123837
The catalytic oxidations of chiral allylic alcohols 2 by manganese complexes of the cyclic triamine 1,4,7-trimethyl-1,4,7-triazacyclononane (tmtacn) 1 and hydrogen peroxide as oxygen donor in the presence of co-catalyst are...
7.
de Boer J, Alsters P, Meetsma A, Hage R, Browne W, Feringa B
Dalton Trans
. 2008 Nov;
(44):6283-95.
PMID: 18985262
The role played by the additives salicylic acid, L-ascorbic acid and oxalic acid in promoting the catalytic activity of [MnIV2(O)3(tmtacn)2](PF6)2 (1(PF6)2, where tmtacn = N,N',N''-trimethyl-1,4,7-triazacyclononane) in the epoxidation and cis-dihydroxylation...
8.
de Boer J, Browne W, Harutyunyan S, Bini L, Tiemersma-Wegman T, Alsters P, et al.
Chem Commun (Camb)
. 2008 Aug;
(32):3747-9.
PMID: 18685764
High turnover enantioselective alkene cis-dihydroxylation is achieved with H(2)O(2) catalysed by manganese based complexes containing chiral carboxylato ligands.
9.
de Boer J, Browne W, Brinksma J, Alsters P, Hage R, Feringa B
Inorg Chem
. 2007 Jul;
46(16):6353-72.
PMID: 17608415
In the presence of carboxylic acids the complex [Mn(IV)2(micro-O)3(tmtacn)2]2+ (1, where tmtacn = N,N',N''-trimethyl-1,4,7-triazacyclononane) is shown to be highly efficient in catalyzing the oxidation of alkenes to the corresponding cis-diol...
10.
Chowdhury S, Witte P, Blank D, Alsters P, Ten Elshof J
Chemistry
. 2006 Jan;
12(11):3061-6.
PMID: 16440385
The recovery of homogeneous polyoxometallate (POM) oxidation catalysts from aqueous and non-aqueous media by a nanofiltration process using mesoporous gamma-alumina membranes is reported. The recovery of Q(12)[WZn(3)(ZnW(9)O(34))(2)] (Q=[MeN(n-C(8)H(17))(3)](+)) from toluene-based...