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Pascal Patschinski

Explore the profile of Pascal Patschinski including associated specialties, affiliations and a list of published articles. Areas
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Articles 5
Citations 20
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Recent Articles
1.
Marin-Luna M, Patschinski P, Zipse H
Chemistry . 2018 Aug; 24(56):15052-15058. PMID: 30070735
Relative rates for the silylation of C4-substituted 1-(naphthalen-1-yl)ethanol substrates with tert-butyldimethylsilyl chloride (TBSCl) in CDCl catalyzed by 9-azajulolidine (TCAP) have been measured. Hammett plot analysis of the resulting selectivity data...
2.
Patschinski P, Zipse H
Org Lett . 2015 Jun; 17(13):3318-21. PMID: 26107932
TBS protection of primary alcohol naphthalen-1-ylmethanol (4a) and secondary alcohol 1-(naphthalen-1-yl)ethanol (4b) has been studied under various reaction conditions. The primary/secondary selectivity is largest in the comparatively slow Lewis base...
3.
Patschinski P, Zhang C, Zipse H
J Org Chem . 2014 Aug; 79(17):8348-57. PMID: 25078902
Reaction rates for the base-catalyzed silylation of primary, secondary, and tertiary alcohols depend strongly on the choice of solvent and catalyst. The reactions are significantly faster in Lewis basic solvents...
4.
Zhang C, Patschinski P, Stephenson D, Panisch R, Wender J, Holthausen M, et al.
Phys Chem Chem Phys . 2014 Jul; 16(31):16642-50. PMID: 24993980
Aiming at the identification of an efficient computational protocol for the accurate NMR assessment of organosilanes in low-polarity organic solvents, (29)Si NMR chemical shifts of a selected set of such...
5.
Hunter H, Hadei N, Blagojevic V, Patschinski P, Achonduh G, Avola S, et al.
Chemistry . 2011 Jun; 17(28):7845-51. PMID: 21656863
Negishi cross-coupling reactions were analyzed in solution by mass spectrometry and NMR spectroscopy to identify both the effect of LiBr as an additive as well as the purpose of 3-dimethyl-2-imidazolidinone...