Nicolaas P van Leest
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Explore the profile of Nicolaas P van Leest including associated specialties, affiliations and a list of published articles.
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23
Citations
258
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Recent Articles
1.
Epping R, de Zwart F, van Leest N, van der Vlugt J, Siegler M, Mathew S, et al.
Inorg Chem
. 2024 Jan;
63(4):1974-1987.
PMID: 38215498
Here, we present the development and characterization of the novel PhenTAA macrocycle as well as a series of [Ni(RPhenTAA)] complexes featuring two sites for ligand-centered redox-activity. These differ in the...
2.
Mekkering M, Biemolt J, de Graaf J, Lin Y, van Leest N, Troglia A, et al.
Catal Sci Technol
. 2023 Apr;
13(7):2255-2260.
PMID: 37025647
Single-atom catalysts often show exceptionally high performance per metal loading. However, the isolated atom sites tend to agglomerate during preparation and/or high-temperature reaction. Here we show that in the case...
3.
van Leest N, Tepaske M, Venderbosch B, Oudsen J, Tromp M, van der Vlugt J, et al.
ACS Catal
. 2022 Aug;
10(14):7449-7463.
PMID: 35912398
The oxidation state of the redox noninnocent tetra-amido macrocyclic ligand (TAML) scaffold was recently shown to affect the formation of nitrene radical species on cobalt(III) upon reaction with PhI=NNs [van...
4.
van Beek C, van Leest N, Lutz M, de Vos S, Klein Gebbink R, de Bruin B, et al.
Chem Sci
. 2022 Mar;
13(7):2094-2104.
PMID: 35308864
Several metalloenzymes, including [FeFe]-hydrogenase, employ cofactors wherein multiple metal atoms work together with surrounding ligands that mediate heterolytic and concerted proton-electron transfer (CPET) bond activation steps. Herein, we report a...
5.
van Leest N, de Zwart F, Zhou M, de Bruin B
JACS Au
. 2021 Sep;
1(8):1101-1115.
PMID: 34467352
Advances in (spectroscopic) characterization of the unusual electronic structures of open-shell cobalt complexes bearing redox-active ligands, combined with detailed mapping of their reactivity, have uncovered several new catalytic radical-type protocols...
6.
Hierlmeier G, Coburger P, Scott D, Maier T, Pelties S, Wolf R, et al.
Chemistry
. 2021 Aug;
27(60):14936-14946.
PMID: 34424579
Reactions of di-tert-butyldiphosphatetrahedrane (1) with cycloocta-1,5-diene- or anthracene-stabilised metalate anions of iron and cobalt consistently afford complexes of the rarely encountered 1,2-diphosphacyclobutadiene ligand, which have previously been very challenging synthetic...
7.
Sang S, Unruh T, Demeshko S, Domenianni L, van Leest N, Marquetand P, et al.
Chemistry
. 2021 Jun;
27(68):16978-16989.
PMID: 34156122
Outer-sphere radical hydrogenation of olefins proceeds via stepwise hydrogen atom transfer (HAT) from transition metal hydride species to the substrate. Typical catalysts exhibit M-H bonds that are either too weak...
8.
van Leest N, de Bruin B
Inorg Chem
. 2021 Jun;
60(12):8380-8387.
PMID: 34096281
Cobalt porphyrin complexes are established catalysts for carbene and nitrene radical group-transfer reactions. The key carbene and mono- and bisnitrene radical complexes coordinated to [Co(TPP)] (TPP = tetraphenylporphyrin) have previously...
9.
Maier T, Gawron M, Coburger P, Bodensteiner M, Wolf R, van Leest N, et al.
Inorg Chem
. 2020 Oct;
59(21):16035-16052.
PMID: 33078926
The synthesis of rare anionic heteroleptic and homoleptic α-diimine iron complexes is described. Heteroleptic BIAN (bis(aryl)iminoacenaphthene) complexes -[K([18]c-6)(thf)] and -[K([18]c-6)(thf)] were synthesized by reduction of the [(BIAN)FeBr] precursor complex using...
10.
Holtrop F, Jupp A, Kooij B, van Leest N, de Bruin B, Chris Slootweg J
Angew Chem Int Ed Engl
. 2020 Aug;
59(49):22210-22216.
PMID: 32840947
Frustrated Lewis pairs (FLPs) are well known for their ability to activate small molecules. Recent reports of radical formation within such systems indicate single-electron transfer (SET) could play an important...