Serhiy Demeshko
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Explore the profile of Serhiy Demeshko including associated specialties, affiliations and a list of published articles.
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184
Citations
919
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Recent Articles
1.
Zinke J, Bruhn C, Demeshko S, Siemeling U
Dalton Trans
. 2025 Mar;
PMID: 40070306
[FeCp*{N(SiMe)}] is a high-spin complex with four unpaired electrons according to SQUID magnetometry and Mößbauer spectroscopy. Its reactions with 4-dimethylaminopyridine (DMAP) and NPrX (X = Cl, Br) respectively afford [FeCp*{N(SiMe)}(DMAP)]...
2.
Meyer F, Demeshko S, Golz C, Townrow O, Fischer M
Dalton Trans
. 2025 Mar;
PMID: 40045774
We present the synthesis and characterization of the parent isolable monomeric triplet titanocene complex, stabilized by the N-heterocyclic carbene (NHC) IMe. Investigated by SQUID magnetometry and quantum-chemical calculations, reactivity studies...
3.
Lindlar Ne Jonasson N, Menke A, Senft L, Squarcina A, Schmidl D, Fisher K, et al.
Inorg Chem
. 2025 Feb;
64(8):3719-3734.
PMID: 39965103
Iron enzymes are ubiquitous in nature. In particular, enzymes with iron-oxygen cofactors as active sites perform a vast variety of reactions. Both iron(III)-hydroxido and iron(IV)-oxido species have been observed to...
4.
Lv Z, Fitterer A, Herbst-Irmer R, Demeshko S, Verplancke H, Holthausen M, et al.
J Am Chem Soc
. 2025 Feb;
147(7):5590-5595.
PMID: 39932156
The Wolff rearrangement (WR) is widely used for the synthesis of ketenes from diazoketones and -esters. Stepwise WR reactions are proposed to proceed through transient carbonylcarbene (R-C-C(O)-R') intermediates, which so...
5.
Neben M, Wegerich N, Al Said T, Thompson R, Demeshko S, Dollberg K, et al.
J Am Chem Soc
. 2025 Jan;
147(6):5330-5339.
PMID: 39878059
Nitrenes (R-N) have been subject to a large body of experimental and theoretical studies. The fundamental reactivity of this important class of transient intermediates has been attributed to their electronic...
6.
Thompson R, Figgins M, Wannipurage D, Renteria-Gomez A, Gogoi A, Telser J, et al.
J Am Chem Soc
. 2025 Jan;
147(6):5350-5359.
PMID: 39873652
Terminal metal-phosphorus (M-P) complexes are of significant contemporary interest as potential platforms for P-atom transfer (PAT) chemistry. Decarbonylation of metal-phosphaethynolate (M-PCO) complexes has emerged as a general synthetic approach to...
7.
Stoian C, Olaru M, Demeshko S, Fischer M, Mebs S, Hupf E, et al.
Chemistry
. 2024 Oct;
31(1):e202403555.
PMID: 39471106
The synthesis, characterization and reactivity of the diferrocenylphosphenium ion [FcP] was extended to the heavier diferrocenylpnictogenium ions, [FcE] (E=As, Sb, Bi). The lighter diferrocenylnitrenium ion, [FcN], was detected by mass...
8.
Spyra C, Hiller D, Eisenlohr K, Dechert S, Demeshko S, Bhattacharya D, et al.
Angew Chem Int Ed Engl
. 2024 Oct;
64(4):e202416022.
PMID: 39364811
Hydrogen bonds involving the oxygen atoms of intermediates that result from copper-mediated O activation play a key role for controlling the reactivity of Cu/O active sites in metalloenzymes and synthetic...
9.
Steube J, Fritsch L, Kruse A, Bokareva O, Demeshko S, Elgabarty H, et al.
Inorg Chem
. 2024 Sep;
63(37):16964-16980.
PMID: 39222251
An isostructural series of Fe, Fe, and Fe complexes [Fe(ImP)] utilizing the ImP 1,1'-(1,3-phenylene)bis(3-methyl-1-imidazol-2-ylidene) ligand, combining -heterocyclic carbenes and cyclometalating functions, is presented. The strong donor motif stabilizes the high-valent...
10.
de Jesus Velazquez-Garcia J, Basuroy K, Wong J, Demeshko S, Meyer F, Kim I, et al.
Chem Sci
. 2024 Aug;
15(33):13531-13540.
PMID: 39183926
The application of two-photon excitation (TPE) in the study of light-responsive materials holds immense potential due to its deeper penetration and reduced photodamage. Despite these benefits, TPE has been underutilised...