Miquel Navarro
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Explore the profile of Miquel Navarro including associated specialties, affiliations and a list of published articles.
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14
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63
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Recent Articles
1.
Landrini M, Navarro M, Campos J, Rocchigiani L
Dalton Trans
. 2024 Dec;
54(3):898-902.
PMID: 39688665
[(L1)Au(μ-H)MCp][BF] complexes (M = Mo and W) featuring cavity-shaped tris-2-(4,4'-di--butylbi-phenylyl)phosphine (L1) have been isolated. The tungsten derivative showed a remarkably fast reactivity in photolytic hydride transfer to generate the mononuclear...
2.
Johnson C, Storm D, Sajjad M, Gyton M, Duckett S, Macgregor S, et al.
Angew Chem Int Ed Engl
. 2024 May;
63(30):e202404264.
PMID: 38699962
Using single-crystal to single-crystal solid/gas reactivity the gold(I) acetylene complex [Au(L1)(η-HC≡CH)][BAr ] is cleanly synthesized by addition of acetylene gas to single crystals of [Au(L1)(CO)][BAr ] [L1=tris-2-(4,4'-di-tert-butylbiphenyl)phosphine, Ar=3,5-(CF)CH]. This simplest...
3.
Beweries T, Buchmeiser M, Champness N, Costas M, Duhme-Klair A, Echeverria J, et al.
Faraday Discuss
. 2023 Jul;
244(0):96-118.
PMID: 37436131
No abstract available.
4.
Navarro M, Holzapfel M, Campos J
Inorg Chem
. 2023 Jun;
62(27):10582-10591.
PMID: 37367828
A cavity-shaped linear gold(I) hydroxide complex acts as a platform to access unusual gold monomeric species. Notably, this sterically crowded gold fragment enables the trapping of CO via insertion into...
5.
Navarro M, Holzapfel M, Campos J
Chempluschem
. 2023 Jun;
88(7):e202300231.
PMID: 37306244
A cavity-shaped gold(I) complex derived from a bulky tri-(ortho-biaryl)-phosphine ligand shows preferred selectivity towards terminal functionalities in the gold(I)-catalysed hydration of alkynes under mild heating due to a well-defined pocket...
6.
Navarro M, Moreno J, Perez-Jimenez M, Campos J
Chem Commun (Camb)
. 2022 Sep;
58(80):11220-11235.
PMID: 36128973
There is growing interest in the design of bimetallic cooperative complexes, which have emerged due to their potential for bond activation and catalysis, a feature widely exploited by nature in...
7.
Navarro M, G Alferez M, de Sousa M, Miranda-Pizarro J, Campos J
ACS Catal
. 2022 Apr;
12(7):4227-4241.
PMID: 35391904
A series of gold(I)-ethylene π-complexes containing a family of bulky phosphine ligands has been prepared. The use of these sterically congested ligands is crucial to stabilize the gold(I)-ethylene bond and...
8.
Navarro M, Miranda-Pizarro J, Moreno J, Navarro-Gilabert C, Fernandez I, Campos J
Chem Commun (Camb)
. 2021 Sep;
57(73):9280-9283.
PMID: 34519292
The use of the exceptionally bulky tris-2-(4,4'-di--butylbiphenylyl)phosphine ligand allows the isolation and complete characterization of the first dicoordinate gold(I)-ethylene adduct, filling a missing fundamental piece on the organometallic chemistry of...
9.
Navarro M, Toledo A, Mallet-Ladeira S, Sosa Carrizo E, Miqueu K, Bourissou D
Chem Sci
. 2021 Jun;
11(10):2750-2758.
PMID: 34084334
The hemilabile P^N ligand MeDalphos enables access to a wide range of stable gold(i) π-complexes with unbiased alkenes and alkynes, as well as electron-rich alkenes and for the first time...
10.
Navarro M, Toledo A, Joost M, Amgoune A, Mallet-Ladeira S, Bourissou D
Chem Commun (Camb)
. 2019 Jun;
55(55):7974-7977.
PMID: 31225552
Tricoordinate gold(i) π-complexes containing P-based chelating ligands (P^P and P^N) were prepared. The structure of the gold(i) styrene complexes has been analysed in detail based on NMR and XRD data....