Stuart A Macgregor
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Explore the profile of Stuart A Macgregor including associated specialties, affiliations and a list of published articles.
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137
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920
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Recent Articles
1.
Gyton M, Sajjad M, Storm D, Altus K, Goodall J, Johnson C, et al.
J Am Chem Soc
. 2025 Feb;
147(10):8706-8719.
PMID: 40000373
The known complex [Ir(Bu-PONOP)MeH][BAr], [Bu-PONOP κ-2,6-(BuPO)CHN); Ar = 3,5-(CF)(CH); 131, 8603], is a robust precursor for single-crystal to single-crystal (SC-SC) C-H activation of methane and ethane at 80 °C. This...
2.
Pecharman A, Carpentier A, Lowe J, Macgregor S, Mahon M, Whittlesey M
Inorg Chem
. 2025 Feb;
64(8):4043-4051.
PMID: 39970375
Reaction of [Ru(IPr)(CO)H][BAr] (; IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene; BAr = B{3,5(CF)CH}) with an excess of ZnH in THF gives the structurally characterized neutral Ru(ZnH) complex [Ru(IPr)(CO)(ZnH)H] () and Ru(ZnH) salt [Ru(IPr)(CO)(ZnH)H][BAr]...
3.
Altus K, Sajjad M, Gyton M, Whitwood A, Page S, Macgregor S, et al.
Organometallics
. 2024 Dec;
43(24):3137-3142.
PMID: 39735277
stabilization of known, but solution unstable, methylidene complex [Ir(Bu-PONOP)(=CH)][BAr ] allows single-crystal to single-crystal solid/gas reactivity associated with the {Ir=CH} group to be studied. Addition of H results in [Ir(Bu-PONOP)(H)][BAr...
4.
Walsh A, Sotorrios L, Cameron R, Pecharman A, Procacci B, Lowe J, et al.
Inorg Chem
. 2024 Nov;
63(48):22944-22954.
PMID: 39564932
The reaction of [Ir(IPr)H][BAr] (; IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene; BAr = B{CH(3,5-CF)}) with ZnMe proceeds with CH elimination to give [Ir(IPr)(IPr')(ZnMe)H][BAr] (, where (IPr') is a cyclometalated IPr ligand). reacts with...
5.
Morton P, Boyce A, Pispek A, Stewart L, Ward D, Tegner B, et al.
Organometallics
. 2024 May;
43(9):974-986.
PMID: 38756993
In order to establish design criteria for Rh C-H borylation catalysts, analogues of the successful catalyst [Rh(Ind)(SIDipp)(COE)] (Ind = η-indenyl, SIDipp = 1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene, and COE = -cyclooctene) were synthesized by...
6.
Johnson C, Storm D, Sajjad M, Gyton M, Duckett S, Macgregor S, et al.
Angew Chem Int Ed Engl
. 2024 May;
63(30):e202404264.
PMID: 38699962
Using single-crystal to single-crystal solid/gas reactivity the gold(I) acetylene complex [Au(L1)(η-HC≡CH)][BAr ] is cleanly synthesized by addition of acetylene gas to single crystals of [Au(L1)(CO)][BAr ] [L1=tris-2-(4,4'-di-tert-butylbiphenyl)phosphine, Ar=3,5-(CF)CH]. This simplest...
7.
Kumar Bisai M, Losiewicz J, Sotorrios L, Nichol G, Dominey A, Cowley M, et al.
Angew Chem Int Ed Engl
. 2024 Apr;
63(24):e202404848.
PMID: 38577790
C-H metalation is the most efficient method to prepare aryl-zinc and -aluminium complexes that are ubiquitous nucleophiles. Virtually all C-H metalation routes to form Al/Zn organometallics require stoichiometric, strong Brønsted...
8.
Audsley G, Carpentier A, Pecharman A, Wright J, Roseveare T, Clark E, et al.
Chem Commun (Camb)
. 2024 Jan;
60(7):874-877.
PMID: 38164828
[Ni(IMes)] reacts with chloroboranes oxidative addition to form rare unsupported Ni-boryls. In contrast, the oxidative addition of hydridoboranes is not observed and products from competing reaction pathways are identified. Computational...
9.
Wheatley M, Zuccarello M, Tsitopoulou M, Macgregor S, Baudoin O
ACS Catal
. 2023 Oct;
13(19):12563-12570.
PMID: 37822862
We report mechanistic studies on the reactivity of different α-substituted C(sp)-H bonds, -CHR (R = H, Me, COMe, CONMe, OMe, and Ph, as well as the cyclopropyl and isopropyl derivatives...
10.
Broumidis E, Thomson C, Gallagher B, Sotorrios L, McKendrick K, Macgregor S, et al.
Org Lett
. 2023 Sep;
25(37):6907-6912.
PMID: 37695021
1,2,6-Thiadiazines treated with visible light and O under ambient conditions are converted into difficult-to-access 1,2,5-thiadiazole 1-oxides (35 examples, yields of 39-100%). Experimental and theoretical studies reveal that 1,2,6-thiadiazines act as...