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Mikhail Agrachev

Explore the profile of Mikhail Agrachev including associated specialties, affiliations and a list of published articles. Areas
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Articles 17
Citations 99
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Recent Articles
1.
Wang H, Agrachev M, Kim H, Truong N, Choi T, Jeschke G, et al.
Science . 2025 Feb; 387(6736):874-880. PMID: 39977516
The reversion of vinyl polymers with carbon-carbon backbones to their monomers represents an ideal path to alleviate the growing plastic waste stream. However, depolymerizing such stable materials remains a challenge,...
2.
Amini S, Oppelt K, Blacque O, Agrachev M, Jeschke G, Zelder F
Chem Sci . 2025 Feb; 16(10):4290-4294. PMID: 39911329
Cofactor F430 is a nickel-containing hydrocorphinato complex that plays important roles in the enzymatic formation and oxidation of methane. In methanotrophic bacteria, F430-dependent methyl-coenzyme M reductase (MCR) catalyses the endergonic...
3.
Moragues T, Agrachev M, Mitchell S, Jeschke G, Perez-Ramirez J, deMello A
Small Methods . 2025 Jan; e2401771. PMID: 39811897
In situ monitoring is essential for catalytic process design, offering real-time insights into active structures and reactive intermediates. Electron paramagnetic resonance (EPR) spectroscopy excels at probing geometric and electronic properties...
4.
Beshara G, Surin I, Agrachev M, Eliasson H, Otroshchenko T, Krumeich F, et al.
EES Catal . 2024 Aug; 2(6):1263-1276. PMID: 39148890
Single-atom catalysts (SACs), possessing a uniform metal site structure, are a promising class of materials for selective oxidations of hydrocarbons. However, their design for targeted applications requires careful choice of...
5.
Fischer J, Agrachev M, Forrer J, Tschaggelar R, Oberhansli O, Jeschke G
Chimia (Aarau) . 2024 Jun; 78(5):326-332. PMID: 38822776
Electron paramagnetic resonance (EPR) spectroscopy is a powerful tool for in situ/operando tracking of catalytic reactions that involve paramagnetic species either as a catalyst (e.g. transition metal ions or defects),...
6.
Araujo T, Giannakakis G, Morales-Vidal J, Agrachev M, Ruiz-Bernal Z, Preikschas P, et al.
Nat Commun . 2024 Apr; 15(1):3101. PMID: 38600146
Metal promotion could unlock high performance in zinc-zirconium catalysts, ZnZrO, for CO hydrogenation to methanol. Still, with most efforts devoted to costly palladium, the optimal metal choice and necessary atomic-level...
7.
Yang Q, Surin I, Geiger J, Eliasson H, Agrachev M, Kondratenko V, et al.
ACS Catal . 2023 Dec; 13(24):15977-15990. PMID: 38125976
The development of selective catalysts for direct conversion of ammonia into nitrous oxide, NO, will circumvent the conventional five-step manufacturing process and enable its wider utilization in oxidation catalysis. Deviating...
8.
Giulimondi V, Ruiz-Ferrando A, Giannakakis G, Surin I, Agrachev M, Jeschke G, et al.
Nat Commun . 2023 Sep; 14(1):5557. PMID: 37689779
Carbon supports are ubiquitous components of heterogeneous catalysts for acetylene hydrochlorination to vinyl chloride, from commercial mercury-based systems to more sustainable metal single-atom alternatives. Their potential co-catalytic role has long...
9.
Faust Akl D, Giannakakis G, Ruiz-Ferrando A, Agrachev M, Medrano-Garcia J, Guillen-Gosalbez G, et al.
Adv Mater . 2023 Mar; 35(26):e2211464. PMID: 36964929
Copper catalysts are attractive candidates for Hg-free vinyl chloride monomer (VCM) production via acetylene hydrochlorination due to their non-toxic nature and high stability. However, the optimal architecture for Cu-based catalysts...
10.
Surin I, Tang Z, Geiger J, Damir S, Eliasson H, Agrachev M, et al.
Adv Mater . 2023 Mar; 35(24):e2211260. PMID: 36863934
Nitrous oxide, N O, exhibits unique reactivity in oxidation catalysis, but the high manufacturing costs limit its prospective uses. Direct oxidation of ammonia, NH , to N O can ameliorate...