Michael G Gardiner
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Explore the profile of Michael G Gardiner including associated specialties, affiliations and a list of published articles.
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245
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Recent Articles
1.
Gome J, Avery Z, Lawson N, Stansfield O, Evans J, Gardiner M, et al.
Angew Chem Int Ed Engl
. 2025 Mar;
:e202503473.
PMID: 40043175
Low symmetry cages are attractive metallo-supramolecular targets, as they may possess different characteristics to their higher symmetry analogues. There are no current generalisable routes for the formation of low-symmetry face-capped...
2.
de Ceuninck van Capelle L, Wales S, Macdonald J, Kruger M, Richardson C, Gardiner M, et al.
J Org Chem
. 2025 Feb;
90(8):3101-3109.
PMID: 39969184
The stereoselective oxidation of benzoazepine-fused isoindolines to benzoazepine-fused isoindole atropodiastereomers is investigated, revealing a central-to-axial chirality conversion. By leveraging the characteristic folded conformation of these C-N atropisomers, Diels-Alder cycloaddition of...
3.
Shang M, He J, Gardiner M, Nitsche C
Org Biomol Chem
. 2025 Jan;
PMID: 39775491
Macrocyclic peptides containing a thiazole heterocycle exhibit fascinating properties in natural products and future therapeutics. We report a biocompatible macrocyclisation approach facilitated by an N-terminal cysteine and C-terminal nitriles. The...
4.
Smith G, Neale S, Evans M, Li X, Wang J, Gardiner M, et al.
Chemistry
. 2024 Nov;
:e202404206.
PMID: 39571111
The potassium aluminyl K[Al(NON)] ([NON]=[O(SiMeNDipp)], Dipp=2,6-iPrCH) reacts with group 14 chloroamidinates E(Am)Cl (E=Ge, Sn, Pb. [Am]=[tBuC(NDipp)]) to form (NON)Al-E(Am) Lewis pairs with unsupported Al-E bonds, including the first structurally authenticated...
5.
de Ceuninck van Capelle L, Rahmannia K, Macdonald J, Richardson C, Gardiner M, Ryan J, et al.
J Org Chem
. 2024 Nov;
89(23):17488-17501.
PMID: 39556601
A two-step formal (4 + 1) annulation-dehydration reaction offers a convenient route to C2-arylated indoles and benzofurans. This reaction exploits the bifunctional reactivity of electron-deficient benzyl chlorides with -sulfonyl-2-aminobenzaldehydes or...
6.
Avery Z, Gardiner M, Preston D
Angew Chem Int Ed Engl
. 2024 Nov;
64(6):e202418079.
PMID: 39536180
Current synthetic methods towards Pt(II) lantern-shaped cages involve the use of dry solvent, inert atmosphere, lengthy reaction times, and highly variable yields if isolated. Starting materials such as [Pt(CHCN)](BF) suffer...
7.
Wu J, Stevens M, Gardiner M, Colebatch A
Dalton Trans
. 2024 Oct;
53(44):18037-18046.
PMID: 39441625
A new unsymmetrical dinucleating phosphino pyridyl 1,8-naphthyridine ligand PNNN is reported. Reaction with CuCl gave the dicopper complex [Cu(μ-Cl)(PNNN)] (1). In contrast, complexation of [RuCl(cymene)] yielded a monometallic species [RuCl(cymene)(PNNN)]Cl...
8.
Pei Z, Connor K, Magann N, Gardiner M, Coote M, Sherburn M
Org Lett
. 2024 Sep;
26(38):8110-8114.
PMID: 39283019
The latent singlet diradical character of the parent -quinonedimethide (-QDM), as revealed by valence bond calculations, is demonstrated experimentally by trapping with the kinetically stable free radical TEMPO at room...
9.
Chen Q, Banwell M, Gardiner M, Lan P, Tan S
J Org Chem
. 2024 Sep;
89(18):13530-13539.
PMID: 39264267
The racemic modification of the α-tropolone-containing sesquiterpene olaximbriside A [viz. (±)-)] has been prepared over 12 steps from the readily accessible decalin derivative . The last two of these steps...
10.
Xu J, Hu Z, Dai L, Yadav A, Jiang Y, Broer A, et al.
Nat Commun
. 2024 Aug;
15(1):7224.
PMID: 39174516
The epithelial neutral amino acid transporter BAT1 (SLC6A19) is the major transporter for the absorption of neutral amino acids in the intestine and their reabsorption in the kidney. Mouse models...