Mehmed Z Ertem
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Explore the profile of Mehmed Z Ertem including associated specialties, affiliations and a list of published articles.
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56
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458
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Recent Articles
1.
Fernandez S, Assaf E, Ahmad S, Travis B, Curley J, Hazari N, et al.
Angew Chem Int Ed Engl
. 2024 Nov;
64(4):e202416061.
PMID: 39571086
The reduction of CO to synthetic fuels is a valuable strategy for energy storage. However, the formation of energy-dense liquid fuels such as methanol remains rare, particularly under low-temperature and...
2.
Wang J, Zhao F, Velasco L, Sauvan M, Moonshiram D, Salati M, et al.
Nat Commun
. 2024 Nov;
15(1):9779.
PMID: 39532887
The selective photoreduction of CO in aqueous media based on earth-abundant elements only, is today a challenging topic. Here we present the anchoring of discrete molecular catalysts on organic polymeric...
3.
Montgomery C, Ertem M, Chevalier L, Dempsey J
J Am Chem Soc
. 2024 Oct;
146(44):30020-30032.
PMID: 39441948
We report the two-electron, one-proton mechanism of cobalt hydride formation for the conversion of [CoCp(PN)(CHCN)] to [HCoCp(PN)]. This complex catalytically converts CO to formate under CO reduction conditions, with hydride...
4.
Elsby M, Kumar A, Daniels L, Ertem M, Hazari N, Mercado B, et al.
Inorg Chem
. 2024 Sep;
63(41):19396-19407.
PMID: 39344157
Six rhenium hydride complexes, [(6,6'-R-bpy)Re(CO)H] (bpy = 2,2'-bipyridine, R = OEt, OMe, NHMe, Me, F, Br), were synthesized. These complexes insert CO to form rhenium formate complexes of the type...
5.
Salati M, Dorchies F, Wang J, Ventosa M, Gonzalez-Carrero S, Bozal-Ginesta C, et al.
Small
. 2024 Sep;
21(7):e2406375.
PMID: 39235360
Light-induced water splitting (hν-WS) for the production of hydrogen as a solar fuel is considered a promising sustainable strategy for the replacement of fossil fuels. An efficient system for hν-WS...
6.
Rotundo L, Ahmad S, Cappuccino C, Pearce A, Nedzbala H, Bottum S, et al.
J Am Chem Soc
. 2024 Aug;
146(36):24742-24747.
PMID: 39190866
We report a series of isomeric, dicationic Re(bpy)(CO)I complexes with bpy (2,2'-bipyridine) modified by two phenyl-CH-(NMe) pendants with cations located at variable distances from the active site for electrocatalytic CO...
7.
Muller A, Ahmad S, Sirlin J, Ertem M, Polyansky D, Grills D, et al.
J Am Chem Soc
. 2024 Mar;
146(15):10524-10536.
PMID: 38507247
The reaction steps for the selective conversion of a transition metal carbonyl complex to a hydroxymethyl complex that releases methanol upon irradiation with visible light have been successfully quantified in...
8.
Polyansky D, Manbeck G, Ertem M
J Phys Chem A
. 2023 Sep;
127(38):7918-7927.
PMID: 37721794
Formal reduction potentials of highly oxidizing and short-lived radical cations of substituted biphenyls generated by pulse radiolysis in 1,2-dichloroethane (DCE) were measured using a redox equilibrium ladder method. The effect...
9.
Banerjee A, Liu Q, Shanklin J, Ertem M
Inorg Chem
. 2023 Jul;
62(29):11402-11413.
PMID: 37430454
Mössbauer spectroscopy provides significant insights into the electronic structure and environment of the metal centers. Herein, we investigate the electronic structures of a set of nonheme diiron complexes by evaluating...
10.
Rotundo L, Ahmad S, Cappuccino C, Polyansky D, Ertem M, Manbeck G
Inorg Chem
. 2023 May;
62(20):7877-7889.
PMID: 37159570
A dicationic Re bipyridine-type complex, -Re(6,6'-(2-((trimethylammonio)-methyl)phenyl)-2,2'-bipyridine )(CO)Cl hexafluorophosphate (), has been synthesized, and its electrochemical behavior under Ar and CO has been investigated. The presence of pendent tetra-alkylammonium cations induces...