Jordi Benet-Buchholz
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Explore the profile of Jordi Benet-Buchholz including associated specialties, affiliations and a list of published articles.
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Citations
816
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Recent Articles
1.
Shi W, Benet-Buchholz J, Kleij A
Nat Commun
. 2025 Feb;
16(1):1372.
PMID: 39910108
Converting carbon dioxide (CO) into valuable heterocycles is of great synthetic value but is usually limited to five- and six-membered ring compounds. Here, we report a catalytic approach for transforming...
2.
Delgado A, Orlando P, Lanzi M, Benet-Buchholz J, Passarella D, Kleij A
Org Lett
. 2024 Aug;
26(36):7596-7600.
PMID: 39213514
Alkyne-functionalized oxetanes are presented as versatile substrates that in combination with amine reagents can be transformed into structurally diverse, chiral γ-amino alcohols featuring a tetrasubstituted tertiary stereocenter under Cu catalysis....
3.
Zeng Q, Nirwan Y, Benet-Buchholz J, Kleij A
Angew Chem Int Ed Engl
. 2024 Apr;
63(26):e202403651.
PMID: 38619179
We report a user-friendly approach for the decarboxylative formation of stereodefined and complex tri- and tetra-substituted olefins from vinyl cyclic carbonates and amines as radical precursors. The protocol relies on...
4.
Shi W, Qiao C, Benet-Buchholz J, Kleij A
ChemSusChem
. 2023 Dec;
17(6):e202301626.
PMID: 38109072
A catalytic domino, three-component reaction has been developed for the transformation of carbon dioxide into functionalized six-membered cyclic carbonates. The catalytic process combines an initial carboxylative cyclization of β-epoxy alcohols...
5.
Ghorai D, Garcia-Roca A, Toth B, Benet-Buchholz J, Kleij A
Angew Chem Int Ed Engl
. 2023 Nov;
62(50):e202314865.
PMID: 37931062
Asymmetric synthesis of small molecules comprising quaternary stereogenic carbon centers represents a challenging objective. Here regio- and enantioselective synthesis of chiral 1,5-dienes featuring quaternary stereocenters is reported via nickel-promoted by...
6.
Garcia-Roca A, Perez-Soto R, Stoica G, Benet-Buchholz J, Maseras F, Kleij A
J Am Chem Soc
. 2023 Mar;
145(11):6442-6452.
PMID: 36883980
Metal-catalyzed propargylic transformations represent a powerful tool in organic synthesis to achieve new carbon-carbon and carbon-heteroatom bonds. However, detailed knowledge about the mechanistic intricacies related to the asymmetric formation of...
7.
Gulyas H, Hayano S, Madarasz A, Papai I, Szabo M, Bucsai A, et al.
Commun Chem
. 2023 Jan;
4(1):71.
PMID: 36697610
Schrock alkylidenes are highly versatile, very active olefin metathesis catalysts, but their pronounced sensitivity to air still hinders their applications. Converting them into more robust but inactive 18-electron adducts was...
8.
Li X, Benet-Buchholz J, Escudero-Adan E, Kleij A
Angew Chem Int Ed Engl
. 2023 Jan;
62(11):e202217803.
PMID: 36637337
A conceptually novel catalytic domino approach is presented for the synthesis of highly functional 1,4-dihydro-2H-1,3-benzoxazine-2-one derivatives. Key to the chemoselectivity is a proper design of the precursor to override thermodynamically...
9.
Jameei Moghaddam N, Gil-Sepulcre M, Wang J, Benet-Buchholz J, Gimbert-Surinach C, Llobet A
Inorg Chem
. 2022 Oct;
61(42):16639-16649.
PMID: 36196853
Two Ni complexes are reported with κ-PN β-diimino (BDI) ligands with the general formula [Ni(XBDI)](BF), where BDI is -(2-(diphenylphosphaneyl)ethyl)-4-((2-(diphenylphosphaneyl)ethyl)imino)pent-2-en-2-amine and X indicates the substituent in the α-carbon intradiimine position, X...
10.
Jiang B, Gil-Sepulcre M, Garrido-Barros P, Gimbert-Surinach C, Wang J, Garcia-Anton J, et al.
Angew Chem Int Ed Engl
. 2022 Aug;
61(40):e202209075.
PMID: 35922381
A cobalt complex bearing a κ-N P ligand is presented (1 or Co (L), where L is (1E,1'E)-1,1'-(pyridine-2,6-diyl)bis(N-(3-(diphenylphosphanyl)propyl)ethan-1-imine). Complex 1 is stable under air at oxidation state Co thanks to...