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Luis F Veiros

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Articles 117
Citations 676
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Recent Articles
1.
Cruz T, Veiros L
Dalton Trans . 2025 Feb; 54(10):4244-4254. PMID: 39912600
This work describes the synthesis, characterization and catalytic hydroboration activity of a family of zinc bis(κ-borohydride) complexes containing borane-functionalized heteroscorpionate ligands. The new zinc bis(κ-borohydride) complexes with R-substituted bis(3,5-dimethylpyrazolyl)methane ligands...
2.
Telo J, Veiros L, Andre V, da Silva J, Justino G, Antunes A
Org Biomol Chem . 2025 Jan; 23(9):2153-2161. PMID: 39850000
Organoselenium compounds have been recognized as potential therapeutic agents against several diseases. Specifically, the incorporation of selenium into natural products has been reported to produce positive synergistic biological effects. We...
3.
Cacho V, Veiros L, Gomes C, Sardo M, Figueira C, Martins A, et al.
Inorg Chem . 2024 Nov; 63(49):23421-23430. PMID: 39589315
The reactivity of ruthenium hydride complexes supported by 2-((di--butylphosphaneyl)methyl)pyridine, and 2-(di--butylphosphaneyl)pyridine, , was explored. The reaction of {Ru(COD)Cl} with in the presence of base and 10 bar of H gave...
4.
Blaha I, Weber S, Dulger R, Veiros L, Kirchner K
ACS Catal . 2024 Sep; 14(17):13174-13180. PMID: 39263541
An additive-free manganese-catalyzed isomerization of terminal alkenes to internal alkenes is described. This reaction is implementing an inexpensive nonprecious metal catalyst. The most efficient catalyst is the borohydride complex -[Mn(dippe)(CO)(κ-BH)]....
5.
Zobernig D, Stoger B, Veiros L, Kirchner K
ACS Catal . 2024 Aug; 14(16):12385-12391. PMID: 39169905
A stereo- and regioselective Mn(I)-catalyzed hydroboration of terminal alkynes with pinacolborane (HBPin) is described. The hydroboration reaction is highly -selective in the case of aryl alkynes and -selective in the...
6.
Di Matteo M, Gagliardi A, Pradal A, Veiros L, Gallou F, Poli G
J Org Chem . 2024 Jul; 89(15):10451-10461. PMID: 39025478
Limonene undergoes a regioselective Pd(II)-catalyzed C(sp)-H/C(sp)-H coupling with acrylic acid esters and amides, α,β-unsaturated ketones, styrenes, and allyl acetate, affording novel 1,3-dienes. DFT computations gave results in accord with the...
7.
Cruz T, Loupy V, Veiros L
Inorg Chem . 2024 Apr; 63(18):8244-8256. PMID: 38656156
The borane-functionalized (BR) bis(3,5-dimethylpyrazolyl)methane () ligands (BR: 9-borabicyclo[3.3.1]nonane or 9-BBN), (BR: BCy), and (BR: B(CF)) were synthesized by the allylation-hydroboration of . Metalation of with ZnCl yielded the heteroscorpionate dichloride...
8.
Weber S, Zobernig D, Stoger B, Veiros L, Kirchner K
Angew Chem Weinheim Bergstr Ger . 2024 Mar; 133(46):24693-24697. PMID: 38505543
A Mn-catalyzed hydroboration of terminal alkenes and a 1,2-diboration of terminal alkynes with pinacolborane (HBPin) is described. For alkenes, anti-Markovnikov hydroboration takes place; for alkynes the reaction proceeds with excellent...
9.
Madeira F, Veiros L, Alves L, Martins A
Molecules . 2023 Dec; 28(24). PMID: 38138486
[(BnCyclam)Y(N(SiMe))] was prepared by reaction of HBnCyclam with Y[N(SiMe)]. The protonation of the macrocycle ligand in [(BnCyclam)Y(N(SiMe))] is observed upon reaction with [HNMe][BPh] leading to the formation of [(HBnCyclam)Y(N(SiMe))][BPh]. DFT...
10.
Schratzberger H, Stoger B, Veiros L, Kirchner K
ACS Catal . 2023 Nov; 13(21):14012-14022. PMID: 37942266
Two bench-stable Fe(II) alkyl complexes [Fe(κPCP-PCP-Pr)(CO)(R)] (R = CHCHCH, CH) were obtained by the treatment of [Fe(κPCP-PCP-Pr)(CO)(H)] with NaNH and subsequent addition of CHCHCHBr and CHI, respectively. The reaction proceeds...