Karthik Devaraj
Overview
Explore the profile of Karthik Devaraj including associated specialties, affiliations and a list of published articles.
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Articles
4
Citations
25
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Recent Articles
1.
Clarke J, Devaraj K, Bestvater B, Kojima R, Eisenberger P, DeJesus J, et al.
Org Biomol Chem
. 2021 Jul;
19(31):6786-6791.
PMID: 34318834
Aldimines and ketimines containing electron-donating and electron-withdrawing groups can be hydrosilylated with borenium catalysts at as low as 1 mol% catalyst loading at room temperature, providing the corresponding secondary amines...
2.
Devaraj K, Ingner F, Sollert C, Gates P, Orthaber A, Pilarski L
J Org Chem
. 2019 Mar;
84(9):5863-5871.
PMID: 30835118
A new, operationally simple approach is presented to access arynes and their fluoride-activated precursors based on Ru-catalyzed C-H silylation of arylboronates. Chromatographic purification may be deferred until after aryne capture,...
3.
Demory E, Devaraj K, Orthaber A, Gates P, Pilarski L
Angew Chem Int Ed Engl
. 2015 Aug;
54(40):11765-9.
PMID: 26270451
(Pinacolato)boryl ortho-silyl(hetero)aryl triflates are presented as a new class of building blocks for arylation. They demonstrate unique versatility by delivering boronate or (hetero)aryne reactivity chemoselectively in a broad range of...
4.
Ru-catalysed C-H arylation of indoles and pyrroles with boronic acids: scope and mechanistic studies
Sollert C, Devaraj K, Orthaber A, Gates P, Pilarski L
Chemistry
. 2015 Feb;
21(14):5380-6.
PMID: 25689052
The Ru-catalysed C2-H arylation of indoles and pyrroles by using boronic acids under oxidative conditions is reported. This reaction can be applied to tryptophan derivatives and tolerates a wide range...