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Jonathan De Roo

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Articles 39
Citations 428
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Recent Articles
1.
Unniram Parambil A, Pokratath R, Parammal M, Dhaene E, Van den Eynden D, Balog S, et al.
Chem Sci . 2024 Oct; PMID: 39386907
The effectiveness of nanocrystals in many applications depends on their surface chemistry. Here, we leverage the atomically precise nature of zirconium and hafnium oxo clusters to gain fundamental insight into...
2.
Seno C, Reichholf N, Salutari F, Spadaro M, Ivanov Y, Divitini G, et al.
J Am Chem Soc . 2024 Jul; 146(30):20550-20555. PMID: 39038812
A careful design of the nanocrystal architecture can strongly enhance the nanocrystal function. So far, this strategy has faced a synthetic bottleneck in the case of refractory oxides. Here we...
3.
Dhaene E, Seno C, De Roo J
Dalton Trans . 2024 Jun; 53(28):11769-11777. PMID: 38939960
We revisited the synthesis of zirconium(IV) and hafnium(IV) alkoxides, namely the metal isopropoxide isopropanol complex (M(OiPr)·iPrOH, M = Zr, Hf) and the metal - and -butoxide (M(OBu) and M(OBu), M...
4.
Parvizian M, Reichholf N, Riaz A, Bhatt P, Regoutz A, De Roo J
Small Methods . 2024 Jun; 8(12):e2400228. PMID: 38859636
Titanium nitride is an exciting plasmonic material, with optical properties similar to gold. However, synthesizing TiN nanocrystals is highly challenging and typically requires solid-state reactions at very high temperatures (800-1000°C)....
5.
Seno C, Pokratath R, Unniram Parambil A, Van den Eynden D, Dhaene E, Prescimone A, et al.
Dalton Trans . 2024 May; 53(23):9862-9873. PMID: 38805233
Group 4 Lewis acids are well-known catalysts and precursors for (non-aqueous) sol-gel chemistry. Titanium, zirconium and hafnium halides, and alkoxy halides are precursors for the controlled synthesis of nanocrystals, often...
6.
Declerck K, Savic N, Moussawi M, Seno C, Pokratath R, De Roo J, et al.
J Am Chem Soc . 2024 Apr; PMID: 38621177
The development of catalysts for controlled fragmentation of proteins is a critical undertaking in modern proteomics and biotechnology. {ZrO}-based metal-organic frameworks (MOFs) have emerged as promising candidates for catalysis of...
7.
Goossens E, Aalling-Frederiksen O, Tack P, Van den Eynden D, Walsh-Korb Z, Jensen K, et al.
J Am Chem Soc . 2024 Apr; 146(15):10723-10734. PMID: 38588404
Nonaqueous sol-gel syntheses have been used to make many types of metal oxide nanocrystals. According to the current paradigm, nonaqueous syntheses have slow kinetics, thus favoring the thermodynamic (crystalline) product....
8.
Goossens E, Deblock L, Caboor L, Van den Eynden D, Josipovic I, Isaacura P, et al.
Small Methods . 2024 Jan; 8(10):e2301499. PMID: 38200600
Vascular corrosion casting is a method used to visualize the three dimensional (3D) anatomy and branching pattern of blood vessels. A polymer resin is injected in the vascular system and,...
9.
Pokratath R, Lermusiaux L, Checchia S, Mathew J, Cooper S, Katja Mathiesen J, et al.
ACS Nano . 2023 Apr; 17(9):8796-8806. PMID: 37093055
One can nowadays readily generate monodisperse colloidal nanocrystals, but the underlying mechanism of nucleation and growth is still a matter of intense debate. Here, we combine X-ray pair distribution function...
10.
Van den Eynden D, Pokratath R, Mathew J, Goossens E, De Buysser K, De Roo J
Chem Sci . 2023 Feb; 14(3):573-585. PMID: 36741516
Metal oxo clusters of the type MO(OH)(OOCR) (M = Zr or Hf) are valuable building blocks for materials science. Here, we synthesize a series of zirconium and hafnium oxo clusters...